Thermodynamics of Nonstoichiometric Nickel Tellurides. I. Heat Capacity and Thermodynamic Functions of the δ Phase from 5 to 350°K
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.contributor.author | Chou, C. | en_US |
dc.contributor.author | Machol, Robert Engel | en_US |
dc.contributor.author | Grønvold, Fredrik | en_US |
dc.date.accessioned | 2010-05-06T21:37:04Z | |
dc.date.available | 2010-05-06T21:37:04Z | |
dc.date.issued | 1958-03 | en_US |
dc.identifier.citation | Westrum, E. F.; Chou, C.; Machol, R. E.; Grønvold, F. (1958). "Thermodynamics of Nonstoichiometric Nickel Tellurides. I. Heat Capacity and Thermodynamic Functions of the δ Phase from 5 to 350°K." The Journal of Chemical Physics 28(3): 497-503. <http://hdl.handle.net/2027.42/70090> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70090 | |
dc.description.abstract | Heat capacities of the nickel tellurides were measured at compositions NiTe1.1 and NiTe2.0 (near limits of homogeneity of the δ phase) and at one intermediate composition, NiTe1.5, from 5 to 350°K. Heat capacity values and entropy and enthalpy increments are tabulated. No evidence of order‐disorder transitions, or thermal anomalies, or of contributions to the thermal properties from the anisotropy or phonon scattering by the holes in the structure on approaching the composition NiTe2 was observed. Although simple additivity of the heat capacities of the constituent elements failed to represent that of the solution compositions adequately, a Kopp‐Neumann treatment in terms of the limiting compositions of the δ phase gives good agreement with the experimental heat capacity and entropy of NiTe1.5 and hence is useful in interpolating to other intermediate compositions. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 479086 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Thermodynamics of Nonstoichiometric Nickel Tellurides. I. Heat Capacity and Thermodynamic Functions of the δ Phase from 5 to 350°K | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan | en_US |
dc.contributor.affiliationother | Chemical Institute A, University of Oslo, Blindern, Norway | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70090/2/JCPSA6-28-3-497-1.pdf | |
dc.identifier.doi | 10.1063/1.1744164 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.owningcollname | Physics, Department of |
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