View Item 

Show simple item record

Measurements of hyperpolarizabilities for some halogenated methanes
dc.contributor.authorFinn, R. S.en_US
dc.contributor.authorWard, J. F.en_US
dc.date.accessioned2010-05-06T21:40:30Z
dc.date.available2010-05-06T21:40:30Z
dc.date.issued1974-01-15en_US
dc.identifier.citationFinn, R. S.; Ward, J. F. (1974). "Measurements of hyperpolarizabilities for some halogenated methanes." The Journal of Chemical Physics 60(2): 454-458. <http://hdl.handle.net/2027.42/70127>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70127
dc.description.abstractdc Electric‐field induced optical second‐harmonic generation has been measured for CH4, CH3F, CH2F2, CHF3, CF4, CClF3, and CBrF3. For CH4 and CF4 the third order hyperpolarizability χ(−2ω; 0,ω,ω) is obtained directly. For the other (dipolar) molecules, a bond additivity estimate for χ(−2ω; 0,ω,ω) is used to extract the second order hyperpolarizability χ(−2ω;ω,ω).Results are compared with various data from the literature: calculated hyperpolarizabilities, and measurements of optical harmonic generation, optical mixing and the Kerr effect. The degree of consistency of the experimental data with a bond additivity model is discussed.en_US
dc.format.extent3102 bytes
dc.format.extent370351 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleMeasurements of hyperpolarizabilities for some halogenated methanesen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumThe Harrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan 48104en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70127/2/JCPSA6-60-2-454-1.pdf
dc.identifier.doi10.1063/1.1681062en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceG. Mayer, C. R. Acad. Sci. B 267, 54 (1968).en_US
dc.identifier.citedreferenceG. Hauchecorne, F. Kerherve, and G. Mayer, J. Phys. (Paris) 32, 47 (1971). In quoting data from this reference we have used the alternative calibration discussed by the authors. This involves normalizing with respect to the measured Kerr coefficient for argon (see Ref. 13) and seems to be more consistent with other normalizations involved in data discussed here.en_US
dc.identifier.citedreferenceR. S. Finn and J. F. Ward, Phys. Rev. Lett. 26, 285 (1971).en_US
dc.identifier.citedreferenceR. S. Finn, “Optical dc‐induced Second Harmonic Generation in Gases,” Thesis, University of Michigan, 1971 (unpublished).en_US
dc.identifier.citedreferenceJ. F. Ward and G. H. C. New, Phys. Rev. 185, 57 (1969).en_US
dc.identifier.citedreferenceB. J. Orr and J. F. Ward, Mol. Phys. 20, 513 (1971).en_US
dc.identifier.citedreferenceR. S. Finn and J. F. Ward, J. Appl. Opt. 11, 2103 (1972).en_US
dc.identifier.citedreferenceP. Sitz and R. Yaris, J. Chem. Phys. 49, 3546 (1968).en_US
dc.identifier.citedreferenceA. D. Buckingham and D. A. Dunmur, Trans. Faraday Soc. 64, 1776 (1968).en_US
dc.identifier.citedreferenceA. D. Buckingham and J. A. Pople, Proc. Phys. Soc. Lond. A 68, 905 (1955); A. D. Buckingham, Proc. Phys. Soc. Lond. A 68, 910 (1955).en_US
dc.identifier.citedreferenceS. Kielich, IEEE J. Quantum Electron. QE5, 562 (1969).en_US
dc.identifier.citedreferenceS. J. Cyvin, J. E. Rauch, and J. C. Decius, J. Chem. Phys. 43, 4083 (1965).en_US
dc.identifier.citedreferenceA. D. Buckingham and B. J. Orr, Trans. Faraday Soc. 65, 673 (1969).en_US
dc.identifier.citedreferenceP. S. Pershan, Phys. Rev. 130, 919 (1963).en_US
dc.identifier.citedreferenceA. D. Buckingham and B. J. Orr, Q. Rev. Chem. Soc. 21, 195 (1967).en_US
dc.identifier.citedreferenceG. P. Arrighini, M. Maestro, and R. Moccia, Symp. Faraday Soc. 2, 48 (1968).en_US
dc.identifier.citedreferenceN. S. Hush and M. L. Williams, Theoret. Chim. Acta. 25, 346 (1972).en_US
dc.identifier.citedreferenceB. F. Levine, Phys. Rev. B 7, 2600 (1973).en_US
dc.owningcollnamePhysics, Department of


Files in this item

Name:
JCPSA6-60-2-454-1.pdf
Size:
361.6KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.