Quantitative tests of mixed crystal exciton theory. II. Energy denominator study of naphthalene 1B2u resonance pairs
dc.contributor.author | Ochs, Frederick W. | en_US |
dc.contributor.author | Kopelman, Raoul | en_US |
dc.date.accessioned | 2010-05-06T21:40:53Z | |
dc.date.available | 2010-05-06T21:40:53Z | |
dc.date.issued | 1977-02-15 | en_US |
dc.identifier.citation | Ochs, Frederick W.; Kopelman, Raoul (1977). "Quantitative tests of mixed crystal exciton theory. II. Energy denominator study of naphthalene 1B2u resonance pairs." The Journal of Chemical Physics 66(4): 1599-1604. <http://hdl.handle.net/2027.42/70131> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70131 | |
dc.description.abstract | A spectroscopic absorption study is presented of 1‐D1C10H7, 2‐D1C10H7, and 1,4‐D2C10H7 resonance pairs in C10D8, over a concentration range of 0.009% to 5% mole, at 2 °K, with a resolution of 0.5 cm−1. The resulting structure is interpreted in terms of the pairwise exciton exchange interactions, M1/2(a+b), Ma, Mb, Mc, Ma+c, and M1/2(a+b)+c. The energy denominator dependence is interpreted in terms of both exciton quasiresonance and exciton superexchange. The three parameter sets derived by Hong and Kopelman to fit earlier data on neat and isotopic mixed crystals are corroborated by this study, as they were in our previous study on monomers (I). However, it was not possible to narrow down completely the choice of parameters. A discussion is given on the feasibility of deriving a unique dispersion relation (and Green’s function) for the first naphthalene singlet exciton and on its likely precision. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 439408 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Quantitative tests of mixed crystal exciton theory. II. Energy denominator study of naphthalene 1B2u resonance pairs | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70131/2/JCPSA6-66-4-1599-1.pdf | |
dc.identifier.doi | 10.1063/1.434081 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | F. W. Ochs, P. N. Prasad, and R. Kopelman, Chem. Phys. 6, 253 (1974). | en_US |
dc.identifier.citedreference | R. Kopelman, J. Chem. Phys. 47, 3227 (1967). | en_US |
dc.identifier.citedreference | D. M. Hanson, J. Chem. Phys. 52, 3409 (1970). | en_US |
dc.identifier.citedreference | H.‐K. Hong and R. Kopelman, Phys. Rev. Lett. 25, 1030 (1970). | en_US |
dc.identifier.citedreference | H.‐K. Hong and R. Kopelman, J. Chem. Phys. 55, 724 (1971). | en_US |
dc.identifier.citedreference | H.‐K. Hong and R. Kopelman, J. Chem. Phys. 57, 3888 (1972). | en_US |
dc.identifier.citedreference | R. Kopelman, in Excited States, edited by E. C. Lim, (Academic, New York, 1975), Vol. II. | en_US |
dc.identifier.citedreference | S. D. Colson, R. Kopelman, and G. W. Robinson, J. Chem. Phys. 47, 27, 5462 (1967). | en_US |
dc.identifier.citedreference | R. Kopelman and J. C. Laufer, in Electronic Density of States, edited by L. H. Bennett, Natl. Bur. Stands. (U.S.G.P.O., Washington, D.C., 1971). | en_US |
dc.identifier.citedreference | J. Hoshen, R. Kopelman, and J. Jortner, Chem. Phys. 10, 185 (1975). | en_US |
dc.identifier.citedreference | V. L. Broude and A. V. Leiderman, JETP Lett. 13, 302 (1971). | en_US |
dc.identifier.citedreference | H.‐K. Hong and G. W. Robinson, J. Chem. Phys. 54, 1369 (1971). | en_US |
dc.identifier.citedreference | C. L. Braun and H. C. Wolf, Chem. Phys. Lett. 9, 260 (1971). | en_US |
dc.identifier.citedreference | E. R. Bernstein, S. D. Colson, R. Kopelman, and G. W. Robinson, J. Chem. Phys. 48, 5596 (1968). | en_US |
dc.identifier.citedreference | D. M. Hanson, R. Kopelman, and G. W. Robinson, J. Chem. Phys. 51, 212 (1969). | en_US |
dc.identifier.citedreference | S. D. Colson, D. M. Hanson, R. Kopelman, and G. W. Robinson, J. Chem. Phys. 48, 2215 (1968). | en_US |
dc.identifier.citedreference | F. Yonezawa and T. Matsubara, Prog. Theor. Phys. (Kyoto) 35, 357, 759 (1966). | en_US |
dc.identifier.citedreference | R. Kopelman, J. Chem. Phys. 47, 2631 (1967). | en_US |
dc.identifier.citedreference | K. E. Mauser, H. Port, and H. C. Wolf, Chem. Phys. 1, 74 (1973). | en_US |
dc.identifier.citedreference | J. Hoshen and R. Kopelman (unpublished). | en_US |
dc.identifier.citedreference | H.‐K. Hong and R. Kopelman, J. Chem. Phys. 55, 5380 (1971). | en_US |
dc.owningcollname | Physics, Department of |
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