Pulsed laser desorption method for volatilizing thermally labile molecules for supersonic jet spectroscopy
dc.contributor.author | Li, Liang | en_US |
dc.contributor.author | Lubman, David M. | en_US |
dc.date.accessioned | 2010-05-06T21:42:04Z | |
dc.date.available | 2010-05-06T21:42:04Z | |
dc.date.issued | 1988-04 | en_US |
dc.identifier.citation | Li, Liang; Lubman, David M. (1988). "Pulsed laser desorption method for volatilizing thermally labile molecules for supersonic jet spectroscopy." Review of Scientific Instruments 59(4): 557-561. <http://hdl.handle.net/2027.42/70144> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70144 | |
dc.description.abstract | A technique using pulsed laser desorption is described as a means of volatilizing nonvolatile and thermally labile molecules into the gas phase for entrainment in supersonic jet expansions. By carefully controlling the laser desorption power and by using a glycerol matrix to provide a thin even film of sample, repetitive desorption can be achieved over an extended period for performing jet spectroscopy. Using resonant two‐photon ionization spectroscopy while monitoring only the molecular ion in a time‐of‐flight mass spectrometer, cold sharp spectra are observed for molecules which are difficult to volatilize by conventional heating methods. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 815305 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/octet-stream | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Pulsed laser desorption method for volatilizing thermally labile molecules for supersonic jet spectroscopy | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70144/2/RSINAK-59-4-557-1.pdf | |
dc.identifier.doi | 10.1063/1.1139832 | en_US |
dc.identifier.source | Review of Scientific Instruments | en_US |
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dc.owningcollname | Physics, Department of |
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