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Pulsed laser desorption method for volatilizing thermally labile molecules for supersonic jet spectroscopy

dc.contributor.authorLi, Liangen_US
dc.contributor.authorLubman, David M.en_US
dc.date.accessioned2010-05-06T21:42:04Z
dc.date.available2010-05-06T21:42:04Z
dc.date.issued1988-04en_US
dc.identifier.citationLi, Liang; Lubman, David M. (1988). "Pulsed laser desorption method for volatilizing thermally labile molecules for supersonic jet spectroscopy." Review of Scientific Instruments 59(4): 557-561. <http://hdl.handle.net/2027.42/70144>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70144
dc.description.abstractA technique using pulsed laser desorption is described as a means of volatilizing nonvolatile and thermally labile molecules into the gas phase for entrainment in supersonic jet expansions. By carefully controlling the laser desorption power and by using a glycerol matrix to provide a thin even film of sample, repetitive desorption can be achieved over an extended period for performing jet spectroscopy. Using resonant two‐photon ionization spectroscopy while monitoring only the molecular ion in a time‐of‐flight mass spectrometer, cold sharp spectra are observed for molecules which are difficult to volatilize by conventional heating methods.en_US
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titlePulsed laser desorption method for volatilizing thermally labile molecules for supersonic jet spectroscopyen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70144/2/RSINAK-59-4-557-1.pdf
dc.identifier.doi10.1063/1.1139832en_US
dc.identifier.sourceReview of Scientific Instrumentsen_US
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dc.owningcollnamePhysics, Department of


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