Dipole Moment Studies. V. The Dipole Moments of the Methylphosphine Boranes
dc.contributor.author | Morse, Joseph G. | en_US |
dc.contributor.author | Parry, Robert Walker | en_US |
dc.date.accessioned | 2010-05-06T21:45:55Z | |
dc.date.available | 2010-05-06T21:45:55Z | |
dc.date.issued | 1972-12-15 | en_US |
dc.identifier.citation | Morse, Joseph G.; Parry, R. W. (1972). "Dipole Moment Studies. V. The Dipole Moments of the Methylphosphine Boranes." The Journal of Chemical Physics 57(12): 5365-5367. <http://hdl.handle.net/2027.42/70185> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70185 | |
dc.description.abstract | Dipole moments of methylphosphine borane, dimethylphosphine borane, and trimethylphosphine borane were determined in benzene solution. After correction for solvent effects the values obtained were: CH3PH2BH3, 4.58 D; (CH3)2PHBH3, 4.78 D; (CH3)3PBH3, 4.97 D. The variation in these moments is interpreted in terms of a polarization model. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 223563 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Dipole Moment Studies. V. The Dipole Moments of the Methylphosphine Boranes | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70185/2/JCPSA6-57-12-5365-1.pdf | |
dc.identifier.doi | 10.1063/1.1678231 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | J. R. Weaver and R. W. Parry, Inorg. Chem. 5, 713 (1966). | en_US |
dc.identifier.citedreference | A. B. Burg and R. I. Wagner, J. Am. Chem. Soc., 75, 3872 (1953). | en_US |
dc.identifier.citedreference | J. R. Weaver, S. G. Shore, and R. W. Parry, J. Chem. Phys. 29, 1 (1958). | en_US |
dc.identifier.citedreference | (a) R. J. W. LeFevre, Dipole Moments (Methuen, London, 1958), (a) p. 2, (b) p. 46, (c) p. 55. | en_US |
dc.identifier.citedreference | J. R. Weaver and R. W. Parry, Inorg. Chem. 5, 703 (1966). | en_US |
dc.identifier.citedreference | G. Kodama, J. R. Weaver, J. LaRochelle, and R. W. Parry, Inorg. Chem. 5, 710 (1966). P. S. Bryan and Robert L. Kuczkowski, Inorg. Chem. 11, 553 (1972), report 4.99±0.2 D4.99±0.2D for (CH3)3PBH3(CH3)3PBH3 and 4.66±0.05 D4.66±0.05D for CH3PH2BH3.CH3PH2BH3. | en_US |
dc.identifier.citedreference | D. R. Lide, Jr., J. Chem. Phys. 27, 343 (1957); 20, 1812 (1952). | en_US |
dc.identifier.citedreference | (a) D. R. Lide, Jr., and D. E. Mann, J. Chem. Phys. (a) 28, 572 (1958). (b) 29, 914 (1958). | en_US |
dc.identifier.citedreference | R. J. W. LeFevre and P. Russell, Trans. Faraday Soc. 43, 374 (1947). | en_US |
dc.identifier.citedreference | T. Kojima, E. Breig, and C. C. Lin, J. Chem. Phys. 35, 2139 (1961). | en_US |
dc.identifier.citedreference | R. Nelson, J. Chem. Phys. 39, 2382 (1963). | en_US |
dc.identifier.citedreference | R. F. Hudson, Structure and Mechanism in Organophosphorus Chemistry (Academic, New York, 1965). | en_US |
dc.owningcollname | Physics, Department of |
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