Restricted Rotator Thermodynamic Properties from the Old Quantum Theory
dc.contributor.author | Halford, J. O. | en_US |
dc.date.accessioned | 2010-05-06T22:02:10Z | |
dc.date.available | 2010-05-06T22:02:10Z | |
dc.date.issued | 1947-09 | en_US |
dc.identifier.citation | Halford, J. O. (1947). "Restricted Rotator Thermodynamic Properties from the Old Quantum Theory." The Journal of Chemical Physics 15(9): 645-651. <http://hdl.handle.net/2027.42/70358> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70358 | |
dc.description.abstract | Accurate partition functions and free energies are calculated for the hindered internal rotator from the old quantum theory based upon the quantization rule of Wilson and Sommerfeld. The description of the system is incomplete and the energy levels may even be incorrectly placed, but the partition functions are surprisingly close to those now accepted as correct. In the course of the development the lowest energy state of the harmonic oscillator turns up in its correct position at the half‐quantum level. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 469177 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Restricted Rotator Thermodynamic Properties from the Old Quantum Theory | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70358/2/JCPSA6-15-9-645-1.pdf | |
dc.identifier.doi | 10.1063/1.1746622 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | J. E. Mayer, S. Brunauer, and M. G. Mayer, J. Am. Chem. Soc. 55, 37 (1933). | en_US |
dc.identifier.citedreference | L. S. Kassel, J. Chem. Phys. 4, 276 (1936). | en_US |
dc.identifier.citedreference | M. L. Eidinoff and J. G. Aston, J. Chem. Phys. 3, 379 (1935). | en_US |
dc.identifier.citedreference | J. O. Halford, J. Chem. Phys. 2, 694 (1934). | en_US |
dc.identifier.citedreference | K. S. Pitzer and W. D. Gwinn, J. Chem. Phys. 10, 428 (1942). | en_US |
dc.identifier.citedreference | J. O. Halford, J. Chem. Phys. 15, 364 (1947). | en_US |
dc.identifier.citedreference | J. S. Koehler and D. M. Dennison, Phys. Rev. 57, 1006 (1940). | en_US |
dc.identifier.citedreference | K. S. Pitzer, J. Chem. Phys. 5, 469 (1937). | en_US |
dc.identifier.citedreference | J. W. Mellor, Higher Mathematics for Students of Chemistry and Physics (Dover Publications, New York, 1946), p. 621. | en_US |
dc.owningcollname | Physics, Department of |
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