An ion trap storage/time‐of‐flight mass spectrometer
dc.contributor.author | Michael, Steven M. | en_US |
dc.contributor.author | Chien, Mingta | en_US |
dc.contributor.author | Lubman, David M. | en_US |
dc.date.accessioned | 2010-05-06T22:12:38Z | |
dc.date.available | 2010-05-06T22:12:38Z | |
dc.date.issued | 1992-10 | en_US |
dc.identifier.citation | Michael, Steven M.; Chien, Mingta; Lubman, David M. (1992). "An ion trap storage/time‐of‐flight mass spectrometer." Review of Scientific Instruments 63(10): 4277-4284. <http://hdl.handle.net/2027.42/70469> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70469 | |
dc.description.abstract | An ion trap/time‐of‐flight (TOF) mass spectrometer combination has been developed in order to combine the storage capabilities of an ion trap with the speed and resolution of a time‐of‐flight device. The ion trap is an rf quadrupole trap which operates in the total storage mode, i.e., with the dc voltage=0 on the end caps and rf voltage on the ring electrode. The trap has an ion storage time of ≥2 s at an rf potential of 310 Vpp. The stored ions are ejected into the time‐of‐flight device using a −150 V dc pulse on the exit end cap which causes the ion trajectories in the trap to become unstable. The ions are mass analyzed using either a linear or reflectron TOF. In the linear mode the resolution is 240 while in the reflectron mode a resolution of 1300 at m/z 93 is achieved. The storage capabilities of this device may have important applications towards enhancing sensitivity, the study of very slow metastable decay, and photodissociation mass spectrometry and spectroscopy. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 1048756 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | An ion trap storage/time‐of‐flight mass spectrometer | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70469/2/RSINAK-63-10-4277-1.pdf | |
dc.identifier.doi | 10.1063/1.1143725 | en_US |
dc.identifier.source | Review of Scientific Instruments | en_US |
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dc.owningcollname | Physics, Department of |
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