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Momentum Transfer to an Atom in a Molecule: Internal Excitation and Bond Dissociation

dc.contributor.authorHsiung, Chi‐huaen_US
dc.contributor.authorGordus, Adon A.en_US
dc.date.accessioned2010-05-06T22:17:42Z
dc.date.available2010-05-06T22:17:42Z
dc.date.issued1962-02-15en_US
dc.identifier.citationHsiung, Chi‐hua; Gordus, Adon A. (1962). "Momentum Transfer to an Atom in a Molecule: Internal Excitation and Bond Dissociation." The Journal of Chemical Physics 36(4): 947-953. <http://hdl.handle.net/2027.42/70523>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70523
dc.description.abstractAn atom will dissociate from a compound if the atom receives a recoil momentum greater than some average value Q0. Considering a polyatomic molecule as composed of point‐mass atoms, there is derived an equation which relates Q0 to the bond energy, bond angles and distances, and masses of the atoms in the molecule. The minimum net recoil energy required for bond rupture, the kinetic energy of the recoiling radicals, and the internal energy of the radical originally bonded to the activated atom are calculated for a series of simple alkyl halides.en_US
dc.format.extent3102 bytes
dc.format.extent473884 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleMomentum Transfer to an Atom in a Molecule: Internal Excitation and Bond Dissociationen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70523/2/JCPSA6-36-4-947-1.pdf
dc.identifier.doi10.1063/1.1732693en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceH. Suess, Z. physik. Chem. B45, 312 (1940).en_US
dc.identifier.citedreferenceSee, for example: R. R. Edwards and T. H. Davies, Nucleonics 2, 44 (1948) or A. C. Wahl and N. A. Bonner, Radioactivity Applied to Chemistry (John Wiley & Sons, Inc., New York, 1951), p. 511.en_US
dc.identifier.citedreferenceH. Steinwedel and J. H. D. Jensen, Naturforsch. A2, 195 (1947).en_US
dc.identifier.citedreferenceK. Svoboda, Zhur. Neorg. Khim. 3, 187 (1958); U.S. Atomic Energy Comm. Nuclear Sci. Abstr. 13, 10954 (1959).en_US
dc.identifier.citedreferenceM. Wolfsberg, J. Chem. Phys. 24, 24 (1956).en_US
dc.owningcollnamePhysics, Department of


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