Dipole Moment Studies. VI. Dipole Moments of the Propylphosphines

Morse, Joseph G.; Parry, Robert Walker

Dipole Moment Studies. VI. Dipole Moments of the Propylphosphines

dc.contributor.author	Morse, Joseph G.	en_US
dc.contributor.author	Parry, Robert Walker	en_US
dc.date.accessioned	2010-05-06T22:22:37Z
dc.date.available	2010-05-06T22:22:37Z
dc.date.issued	1972-12-15	en_US
dc.identifier.citation	Morse, Joseph G.; Parry, R. W. (1972). "Dipole Moment Studies. VI. Dipole Moments of the Propylphosphines." The Journal of Chemical Physics 57(12): 5367-5371. <http://hdl.handle.net/2027.42/70575>	en_US
dc.identifier.uri	https://hdl.handle.net/2027.42/70575
dc.description.abstract	The dipole moments of mono‐n‐propylphosphine and mono‐i‐propylphosphine, as measured in the gas phase with a heterodyne beat apparatus, are 1.09±0.06 and 1.22±0.03 D, respectively. The moments of mono‐n‐propylphosphine, di‐n‐propylphosphine, and tri‐n‐propylphosphine as measured in benzene solution and corrected for solvent effect are 1.17±0.05, 1.22±0.05, and 1.16±0.08 D, respectively. The moments for mono‐i‐propylphosphine, di‐i‐propylphosphine, and tri‐i‐propylphosphine as measured in benzene solution and corrected for solvent effects are 1.13±0.03, 1.32±0.12, and 1.32±0.04 D, respectively. Discrepancies between gas phase and solution values are considered, and values for each series are discussed in terms of a bond polarization model.	en_US
dc.format.extent	3102 bytes
dc.format.extent	344375 bytes
dc.format.mimetype	text/plain
dc.format.mimetype	application/pdf
dc.publisher	The American Institute of Physics	en_US
dc.rights	© The American Institute of Physics	en_US
dc.title	Dipole Moment Studies. VI. Dipole Moments of the Propylphosphines	en_US
dc.type	Article	en_US
dc.subject.hlbsecondlevel	Physics	en_US
dc.subject.hlbtoplevel	Science	en_US
dc.description.peerreviewed	Peer Reviewed	en_US
dc.contributor.affiliationum	Department of Chemistry, The University of Michigan, Ann Arbor, Michigan	en_US
dc.contributor.affiliationother	Department of Chemistry, Utah State University, Logan, Utah 84321	en_US
dc.description.bitstreamurl	http://deepblue.lib.umich.edu/bitstream/2027.42/70575/2/JCPSA6-57-12-5367-1.pdf
dc.identifier.doi	10.1063/1.1678232	en_US
dc.identifier.source	The Journal of Chemical Physics	en_US
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dc.owningcollname	Physics, Department of

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