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The Infra‐Red Absorption Spectrum of Boron Trifluoride

dc.contributor.authorGage, D. M.en_US
dc.contributor.authorBarker, E. F.en_US
dc.date.accessioned2010-05-06T22:34:19Z
dc.date.available2010-05-06T22:34:19Z
dc.date.issued1939-07en_US
dc.identifier.citationGage, D. M.; Barker, E. F. (1939). "The Infra‐Red Absorption Spectrum of Boron Trifluoride." The Journal of Chemical Physics 7(7): 455-459. <http://hdl.handle.net/2027.42/70698>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70698
dc.description.abstractThe infra‐red absorption spectrum of BF3 has been studied under high resolution from 400 cm—1 to 3000 cm—1. The active fundamentals v2, v3 and v4 and the overtone 2v3 have been observed. The parallel fundamental v2 has been partially resolved and the value of the moment of inertia A found to be 79×10—40 g cm2. The B☒F distance is 1.29×10—8 cm. The isotope effect due to the two isotopes of boron was observed in all bands. The appearance of the unresolved bands v4 and 2v3 is shown to be greatly influenced by the interaction between vibration and rotation.en_US
dc.format.extent3102 bytes
dc.format.extent308229 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleThe Infra‐Red Absorption Spectrum of Boron Trifluorideen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumUniversity of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70698/2/JCPSA6-7-7-455-1.pdf
dc.identifier.doi10.1063/1.1750471en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.identifier.citedreferenceC. R. Bailey, J. B. Hale, and J. W. Thompson, Proc. Roy. Soc. 161, 107 (1937).en_US
dc.identifier.citedreferenceJ. D. Hardy, Phys. Rev. 38, 2162 (1931).en_US
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dc.owningcollnamePhysics, Department of


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