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Effects of alternation in some quasi‐one‐dimensional magnetic materials

dc.contributor.authorKirk, Martin L.en_US
dc.contributor.authorHatfield, William E.en_US
dc.contributor.authorLah, Myoung Sooen_US
dc.contributor.authorKessissoglou, Dimitrien_US
dc.contributor.authorPecoraro, Vincent L.en_US
dc.contributor.authorMorgan, Larry W.en_US
dc.contributor.authorPetersen, John D.en_US
dc.date.accessioned2010-05-06T22:34:35Z
dc.date.available2010-05-06T22:34:35Z
dc.date.issued1991-04-15en_US
dc.identifier.citationKirk, Martin L.; Hatfield, William E.; Lah, Myoung Soo; Kessissoglou, Dimitri; Pecoraro, Vincent L.; Morgan, Larry W.; Petersen, John D. (1991). "Effects of alternation in some quasi‐one‐dimensional magnetic materials." Journal of Applied Physics 69(8): 6013-6015. <http://hdl.handle.net/2027.42/70701>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70701
dc.description.abstractExchange coupling in Cu(II) and Mn(III) compounds with unusual structures is discussed. {[Cu(bipyrimidine)(OH)(H2O)] (ClO4)}n has an alternatingly bridged structure with alternating ferromagnetic (+167.6 cm−1 through the hydroxo bridge) and antiferromagnetic (−79.8 cm−1 through the bipyrimidine bridge) interactions. Copper(II) phthalate monohydrate has alternating next‐nearest‐neighbor exchange with J=−12.3 cm−1 and α=0.06. This is the first member of this class. The compound K2[Mn(III) (salicylate)2][Mn(III) (salicylate)2]{CH3OH]2 has manganese ions in two environments alternating along the chain. A modified model for the chain is presented, and exchange coupling is found to be small since magnetic orbitals are not linked by the bridging ligand.en_US
dc.format.extent3102 bytes
dc.format.extent419070 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleEffects of alternation in some quasi‐one‐dimensional magnetic materialsen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109‐1055en_US
dc.contributor.affiliationotherDepartment of Chemistry, The University of North Carolina, Chapel Hill, North Carolina 27599‐3290en_US
dc.contributor.affiliationotherDepartment of Chemistry, Clemson, University, Clemson, South Carolina 29634en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70701/2/JAPIAU-69-8-6013-1.pdf
dc.identifier.doi10.1063/1.347796en_US
dc.identifier.sourceJournal of Applied Physicsen_US
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dc.owningcollnamePhysics, Department of


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