Effects of alternation in some quasi‐one‐dimensional magnetic materials
dc.contributor.author | Kirk, Martin L. | en_US |
dc.contributor.author | Hatfield, William E. | en_US |
dc.contributor.author | Lah, Myoung Soo | en_US |
dc.contributor.author | Kessissoglou, Dimitri | en_US |
dc.contributor.author | Pecoraro, Vincent L. | en_US |
dc.contributor.author | Morgan, Larry W. | en_US |
dc.contributor.author | Petersen, John D. | en_US |
dc.date.accessioned | 2010-05-06T22:34:35Z | |
dc.date.available | 2010-05-06T22:34:35Z | |
dc.date.issued | 1991-04-15 | en_US |
dc.identifier.citation | Kirk, Martin L.; Hatfield, William E.; Lah, Myoung Soo; Kessissoglou, Dimitri; Pecoraro, Vincent L.; Morgan, Larry W.; Petersen, John D. (1991). "Effects of alternation in some quasi‐one‐dimensional magnetic materials." Journal of Applied Physics 69(8): 6013-6015. <http://hdl.handle.net/2027.42/70701> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70701 | |
dc.description.abstract | Exchange coupling in Cu(II) and Mn(III) compounds with unusual structures is discussed. {[Cu(bipyrimidine)(OH)(H2O)] (ClO4)}n has an alternatingly bridged structure with alternating ferromagnetic (+167.6 cm−1 through the hydroxo bridge) and antiferromagnetic (−79.8 cm−1 through the bipyrimidine bridge) interactions. Copper(II) phthalate monohydrate has alternating next‐nearest‐neighbor exchange with J=−12.3 cm−1 and α=0.06. This is the first member of this class. The compound K2[Mn(III) (salicylate)2][Mn(III) (salicylate)2]{CH3OH]2 has manganese ions in two environments alternating along the chain. A modified model for the chain is presented, and exchange coupling is found to be small since magnetic orbitals are not linked by the bridging ligand. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 419070 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Effects of alternation in some quasi‐one‐dimensional magnetic materials | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109‐1055 | en_US |
dc.contributor.affiliationother | Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina 27599‐3290 | en_US |
dc.contributor.affiliationother | Department of Chemistry, Clemson, University, Clemson, South Carolina 29634 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70701/2/JAPIAU-69-8-6013-1.pdf | |
dc.identifier.doi | 10.1063/1.347796 | en_US |
dc.identifier.source | Journal of Applied Physics | en_US |
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dc.owningcollname | Physics, Department of |
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