View Item 

Show simple item record

The structures and dipole moments of Ar–PF3 and Kr–PF3
dc.contributor.authorTaleb‐bendiab, Amineen_US
dc.contributor.authorLaBarge, Marabeth S.en_US
dc.contributor.authorLohr, Lawrence L. Jr.en_US
dc.contributor.authorTaylor, Robert Cooperen_US
dc.contributor.authorHillig, Kurt W. IIen_US
dc.contributor.authorKuczkowski, Robert L.en_US
dc.contributor.authorBohn, Robert K.en_US
dc.date.accessioned2010-05-06T22:38:56Z
dc.date.available2010-05-06T22:38:56Z
dc.date.issued1989-06-15en_US
dc.identifier.citationTaleb‐Bendiab, Amine; LaBarge, Marabeth S.; Lohr, Lawrence L.; Taylor, Robert C.; Hillig, Kurt W.; Kuczkowski, Robert L.; Bohn, Robert K. (1989). "The structures and dipole moments of Ar–PF3 and Kr–PF3." The Journal of Chemical Physics 90(12): 6949-6955. <http://hdl.handle.net/2027.42/70747>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70747
dc.description.abstractThe complexes of PF3 with Ar and Kr, were studied by Fourier transform microwave spectroscopy. The force constants and amplitudes of vibration for the van der Waals modes of the complexes and the average moments of inertia and structural parameters were estimated from the centrifugal distortion constants. The distance (Rc.m. )ave between the rare‐gas atom and the center of mass of PF3 is 3.959 Å for the Ar complex and 4.077 Å for Kr while the angle (θc.m. )ave between the Rc.m. vector and the C3 axis of the PF3 is 69.30° and 67.25°, respectively. The dipole moments of both complexes and of free PF3 were determined. The induced dipole components estimated for the rare gas using electric fields from ab initio calculations of PF3 agree with the experimental values for a conformation with the rare gas over a PF2 face. The PF2 face conformation is also consistent with the observed and ab initio estimates of the 83 Kr nuclear quadrupole coupling constant for the 83 Kr–PF3 species.en_US
dc.format.extent3102 bytes
dc.format.extent587699 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleThe structures and dipole moments of Ar–PF3 and Kr–PF3en_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109en_US
dc.contributor.affiliationotherDepartment of Chemistry, University of Connecticut, Storrs, Connecticut 06268en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70747/2/JCPSA6-90-12-6949-1.pdf
dc.identifier.doi10.1063/1.456270en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceK. W. Hillig II, J. Matos, A. Scioly, and R. L. Kuczkowski, Chem. Phys. Lett. 133, 359 (1987).en_US
dc.identifier.citedreferenceM. S. Labarge, E. R. Bittner, K. W. Hillig II, and R. L. Kuczkowski, J. Mol. Struct. 189, 105 (1988).en_US
dc.identifier.citedreferenceR. K. Bohn, K. W. Hillig II, and R. L. Kuczkowski, J. Phys. Chem. (in press).en_US
dc.identifier.citedreferenceJ. S. Muenter, J. Chem. Phys. 48, 4544 (1968).en_US
dc.identifier.citedreferenceW. Gordy and R. L. Cook, Molecular Microwave Spectra (Wiley, New York, 1984), Chap. 8.en_US
dc.identifier.citedreferenceV. Typke, J. Mol. Spectrosc. 63, 170 (1976).en_US
dc.identifier.citedreferenceRef. 5, pp. 413–418.en_US
dc.identifier.citedreferenceS. N. Ghosh, R. Trambarulo, and W. Gordy, J. Chem. Phys. 21, 308 (1953).en_US
dc.identifier.citedreferenceD. R. Herschbach and V. W. Laurie, J. Chem. Phys. 37, 1668, 1687 (1962).en_US
dc.identifier.citedreference(a) J. A. Shea, W. G. Read, and E. J. Campbell, J. Chem. Phys. 79, 2559 (1983); (b) M. R. Keenan, D. B. Wozniak, and W. H. Flygare, 75, 631 (1981).en_US
dc.identifier.citedreferenceC. E. Small and J. G. Smith, J. Mol. Spectrosc. 73, 215 (1978).en_US
dc.identifier.citedreferenceY. Kawashima and A. P. Cox, J. Mol. Spectrosc. 65, 319 (1977).en_US
dc.identifier.citedreferenceP. D. Aldrich, A. C. Legon, and W. H. Flygare, J. Chem. Phys. 75, 2126 (1981).en_US
dc.identifier.citedreferenceM. S. LaBarge, K. W. Hillig II, and R. L. Kuczkowski (unpublished results).en_US
dc.identifier.citedreferenceRef. 5, pp. 570–581.en_US
dc.identifier.citedreferenceS. J. Harris, K. C. Janda, S. E. Novick, and W. Klemperer, J. Chem. Phys. 63, 881 (1975).en_US
dc.identifier.citedreferenceC. H. Joyner, T. A. Dixon, F. A. Baiocchi, and W. Klemperer, J. Chem. Phys. 75, 5285 (1981).en_US
dc.identifier.citedreferenceS. Wolfram, Mathematical A System for Doing Mathematics (Addison‐Wesley, New York, 1988); Wolfram Research Inc., Champaign, Illinois.en_US
dc.identifier.citedreferenceR. H. Orcutt and R. H. Cole, J. Chem. Phys. 46, 697 (1967).en_US
dc.identifier.citedreferenceThis work.en_US
dc.identifier.citedreferenceR. G. Stone, J. M. Pochan, and W. H. Flygare, Inorg. Chem. 8, 2647 (1969).en_US
dc.identifier.citedreferenceM. J. Frisch, J. S. Binkley, H. B. Schlegel, K. Raghavachari, C. F. Melius, R. L. Martin, J. J. P. Stewart, F. W. Bobrowicz, C. M. Rohlfing, L. R. Kahn, D. J. DeFrees, R. Seeger, R. A. Whiteside, D. J. Fox, E. M. Fluder, and J. A. Pople, GAUSSIAN86 (Carnegie‐Mellon Quantum Chemistry Publishing Unit, Pittsburgh, PA, 1986).en_US
dc.identifier.citedreferenceR. M. Sternheimer, Phys. Rev. 80, 102 (1950); 84, 244 (1951); 86, 316 (1952); 95, 736 (1954).en_US
dc.identifier.citedreferenceR. M. Sternheimer and H. M. Foley, Phys. Rev. 92, 1460 (1953); 102, 731 (1956).en_US
dc.identifier.citedreferenceH. M. Foley, R. M. Sternheimer, and D. Tycko, Phys. Rev. 93, 734 (1954).en_US
dc.identifier.citedreferenceE. J. Campbell, L. W. Buxton, M. R. Keenan, and W. H. Flygare, Phys. Rev. A 24, 812 (1981).en_US
dc.identifier.citedreferenceL. W. Buxton, E. J. Campbell, M. R. Keenan, T. J. Balle, and W. H. Flygare, Chem. Phys. 54, 173 (1981).en_US
dc.identifier.citedreferenceL. W. Buxton, E. J. Campbell, and W. H. Flygare, Chem. Phys. 59, 55 (1981).en_US
dc.identifier.citedreferenceE. J. Campbell, L. W. Buxton, and A. C. Legon, J. Chem. Phys. 78, 3483 (1983).en_US
dc.identifier.citedreferenceJ. A. Shea and E. J. Campbell, J. Chem. Phys. 81, 5326 (1984).en_US
dc.identifier.citedreferenceC. H. Townes and B. P. Dailey, J. Chem. Phys. 17, 782 (1949).en_US
dc.identifier.citedreferenceW. L. Faust and L. Y. Chow Chiu, Phys. Rev. 129, 1214 (1963).en_US
dc.identifier.citedreferenceX. Husson, J.‐P. Grandin, and H. Kucal, J. Phys. B 12, 3883 (1979).en_US
dc.identifier.citedreferenceR. P. McEachran, A. D. Stauffer, and S. Greita, J. Phys. B 12, 3119 (1979).en_US
dc.identifier.citedreferenceF. D. Feiock and W. R. Johnson, Phys. Rev. 187, 39 (1969).en_US
dc.identifier.citedreference(a) Z. Latajka and S. Scheiner, J. Mol. Struct. (in press); (b) private communication.en_US
dc.identifier.citedreferenceSee AIP document no. PAPS JCPSA‐90‐6949‐5 for 5 pages of tables of Ar‐PF3Ar‐PF3 and 83Kr‐PF3.83Kr‐PF3. Order by PAPS number and journal reference from American Institute of Physics, Physics Auxiliary Publication Service, 335 East 45th Street, New York, NY 10017. The price is $1.50 for each microfiche (98 pages) or $5.00 for photocopies of up to 30 pages, and $0.15 for each additional page over 30 pages. Airmail additional. Make checks payable to the American Institute of Physics.en_US
dc.owningcollnamePhysics, Department of


Files in this item

Name:
JCPSA6-90-12-6949-1.pdf
Size:
573.9KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.