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Electron Relaxation and Molecular Vibrations: Triatomic Systems of the First‐Row Elements, the Methyl Radical, and Diazomethane and Ketene
dc.contributor.authorBurdett, Jeremyen_US
dc.date.accessioned2010-05-06T22:53:37Z
dc.date.available2010-05-06T22:53:37Z
dc.date.issued1970-03-15en_US
dc.identifier.citationBurdett, Jeremy (1970). "Electron Relaxation and Molecular Vibrations: Triatomic Systems of the First‐Row Elements, the Methyl Radical, and Diazomethane and Ketene." The Journal of Chemical Physics 52(6): 2983-2992. <http://hdl.handle.net/2027.42/70902>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70902
dc.description.abstractThe well‐known second‐order perturbation method is used to correlate the bond–bond interaction constants in ground and excited electronic states of triatomic systems of the first‐row elements, and unusual force constants in diazomethane and ketene with the effect of electron relaxation. The third‐ and fourth‐order perturbation schemes are used to determine qualitatively the contributions to the third‐ and fourth‐order parts of the vibrational potential function of carbon dioxide, by the electron relaxation effect. The fourth‐order theory is used to rationalize the negative anharmonicities observed in ketene, diazomethane, the methyl radical, and planar excited states of ammonia.en_US
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleElectron Relaxation and Molecular Vibrations: Triatomic Systems of the First‐Row Elements, the Methyl Radical, and Diazomethane and Keteneen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70902/2/JCPSA6-52-6-2983-1.pdf
dc.identifier.doi10.1063/1.1673427en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.owningcollnamePhysics, Department of


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