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Microwave spectrum and structure of the dimethylamine dimer: Evidence for a cyclic structure
dc.contributor.authorTubergen, Michael J.en_US
dc.contributor.authorKuczkowski, Robert L.en_US
dc.date.accessioned2010-05-06T22:55:30Z
dc.date.available2010-05-06T22:55:30Z
dc.date.issued1994-03-01en_US
dc.identifier.citationTubergen, Michael J.; Kuczkowski, Robert L. (1994). "Microwave spectrum and structure of the dimethylamine dimer: Evidence for a cyclic structure." The Journal of Chemical Physics 100(5): 3377-3383. <http://hdl.handle.net/2027.42/70922>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70922
dc.description.abstractRotational spectra have been measured for six isotopomers of the dimethylamine dimer using a Fourier‐transform microwave spectrometer. No tunneling splittings were observed for either the a‐ or c‐type rotational transitions and the spectra could be fit to a rigid rotor Hamiltonian including centrifugal distortion terms. Possible dimer structures are discussed and compared to the experimentally determined moments of inertia, dipole moments, and nuclear quadrupole coupling constants. A cyclic structure with Cs symmetry was found to best reproduce the inertial data. The structure of the dimethylamine dimer is compared to the theoretical and experimental structures for the ammonia dimer.en_US
dc.format.extent3102 bytes
dc.format.extent901065 bytes
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dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleMicrowave spectrum and structure of the dimethylamine dimer: Evidence for a cyclic structureen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumThe Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109‐1055en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70922/2/JCPSA6-100-5-3377-1.pdf
dc.identifier.doi10.1063/1.466381en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.owningcollnamePhysics, Department of


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