(N2O)2⋅SO2:(N2O)2⋅SO2: Rotational spectrum and structure of the first van der Waals trimer containing sulfur dioxide
dc.contributor.author | Peebles, Rebecca A. | en_US |
dc.contributor.author | Kuczkowski, Robert L. | en_US |
dc.date.accessioned | 2010-05-06T22:55:41Z | |
dc.date.available | 2010-05-06T22:55:41Z | |
dc.date.issued | 2000-05-22 | en_US |
dc.identifier.citation | Peebles, Rebecca A.; Kuczkowski, Robert L. (2000). "(N2O)2⋅SO2:(N2O)2⋅SO2: Rotational spectrum and structure of the first van der Waals trimer containing sulfur dioxide." The Journal of Chemical Physics 112(20): 8839-8846. <http://hdl.handle.net/2027.42/70924> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70924 | |
dc.description.abstract | The trimer (N2O)2⋅SO2(N2O)2⋅SO2 has been studied by Fourier transform microwave spectroscopy. The rotational constants for the normal species are A = 1369.1014(11) MHz,A=1369.1014(11)MHz, B = 1115.5816(11) MHz,B=1115.5816(11)MHz, and C = 730.5790(4) MHz.C=730.5790(4)MHz. Five isotopomers of the complex have been studied, allowing a determination of its structure. The configuration aligns the centers-of-mass of the three monomers in an approximate equilateral triangle. The monomers twist relative to this plane so that the two N2OsN2Os are intermediate between T-shaped and crossed rather than the usual slipped-parallel planar. The SO2SO2 is oriented so that its oxygens are straddling one N2ON2O (similar to the N2O⋅SO2N2O⋅SO2 dimer), while its sulfur is closest to the oxygen end of the other N2O.N2O. The dipole moment of (15N2O)2⋅SO2(15N2O)2⋅SO2 was measured, giving μa = 0.606(1) D,μa=0.606(1)D, μb = 1.256(2) D,μb=1.256(2)D, μc = 0.058(2) D,μc=0.058(2)D, and μtotal = 1.396(2) D.μtotal=1.396(2)D. A semiempirical model has been used to predict the trimer structure, and comparison is made with this model as well as with the dimer N2O⋅SO2.N2O⋅SO2. © 2000 American Institute of Physics. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 223031 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | (N2O)2⋅SO2:(N2O)2⋅SO2: Rotational spectrum and structure of the first van der Waals trimer containing sulfur dioxide | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70924/2/JCPSA6-112-20-8839-1.pdf | |
dc.identifier.doi | 10.1063/1.481498 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.owningcollname | Physics, Department of |
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