Electric Field Gradients at 57Fe in ZnFe2O4 and CdFe2O4
dc.contributor.author | Evans, B. J. | en_US |
dc.contributor.author | Hafner, S. S. | en_US |
dc.contributor.author | Weber, H. P. | en_US |
dc.date.accessioned | 2010-05-06T23:02:07Z | |
dc.date.available | 2010-05-06T23:02:07Z | |
dc.date.issued | 1971-12-01 | en_US |
dc.identifier.citation | Evans, B. J.; Hafner, S. S.; Weber, H. P. (1971). "Electric Field Gradients at 57Fe in ZnFe2O4 and CdFe2O4." The Journal of Chemical Physics 55(11): 5282-5288. <http://hdl.handle.net/2027.42/70992> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70992 | |
dc.description.abstract | The nuclear quadrupole coupling constants and isomer shifts of 57Fe in the spinels ZnFe2O4 and CdFe2O4 were measured using the Mössbauer effect. The signs of the quadrupole coupling constants were determined from spectra which were taken in an applied magnetic field. The sign is negative in both spinels. The isomer shifts and Fe☒O distances indicate that Fe3+ in ZnFe2O4 is somewhat more covalently bonded than in CdFe2O4. The external field gradients at the Fe3+ positions can be interpreted in terms of the ionic point‐multipole model modified by some charge transfer between oxygen and the cations. The point charge contribution to the field gradient is positive in case of ZnFe2O4 and nearly zero in case of CdFe2O4; the predominant contribution is due to the electric dipole moments of the oxygen ions and is negative. The dipole polarizability of the oxygen ion which gave the best fit is αD = 0.8 Å3αD=0.8Å3. The effect of charge transfer on the ionic field gradient is small. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 471871 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Electric Field Gradients at 57Fe in ZnFe2O4 and CdFe2O4 | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Geology and Mineralogy, The University of Michigan, Ann Arbor, Michigan 48104 | en_US |
dc.contributor.affiliationother | Department of the Geophysical Sciences, The University of Chicago, Chicago, Illinois 60637 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70992/2/JCPSA6-55-11-5282-1.pdf | |
dc.identifier.doi | 10.1063/1.1675668 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.owningcollname | Physics, Department of |
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