Spin Resonance of SnO2:V and the Vanadium 3d Electron Orbital
dc.contributor.author | Kikuchi, Chihiro | en_US |
dc.contributor.author | Chen, Inan | en_US |
dc.contributor.author | From, William H. | en_US |
dc.contributor.author | Dorain, Paul B. | en_US |
dc.date.accessioned | 2010-05-06T23:18:03Z | |
dc.date.available | 2010-05-06T23:18:03Z | |
dc.date.issued | 1965-01-01 | en_US |
dc.identifier.citation | Kikuchi, Chihiro; Chen, Inan; From, William H.; Dorain, Paul B. (1965). "Spin Resonance of SnO2:V and the Vanadium 3d Electron Orbital." The Journal of Chemical Physics 42(1): 181-185. <http://hdl.handle.net/2027.42/71160> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/71160 | |
dc.description.abstract | The ESR spectrum of SnO2 containing about 0.5% vanadium observed in K band at liquid‐nitrogen temperature shows two sets of shfs. Relative intensity measurements show that the large shfs (168 G) is due to the two tins located along the c axis and the small shfs (28 G) due to the four tins lying in a diagonal plane of the unit cell containing four oxygens. The large shfs is largely isotropic, with an axial maximum along the c axis. This suggests that the ground electron level is 3d(x2−y2). The next level is 3d(xz). This is deduced from the g values (gxx = 1.939,gyy = 1.903,and gzz = 1.943)(gxx=1.939,gyy=1.903,andgzz=1.943). | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 294509 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Spin Resonance of SnO2:V and the Vanadium 3d Electron Orbital | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Nuclear Engineering, University of Michigan, Ann Arbor, Michigan | en_US |
dc.contributor.affiliationother | Wayland Laboratory, Raytheon, Wayland, Massachusetts | en_US |
dc.contributor.affiliationother | Department of Chemistry, Brandeis University, Waltham, Massachusetts | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/71160/2/JCPSA6-42-1-181-1.pdf | |
dc.identifier.doi | 10.1063/1.1695667 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.owningcollname | Physics, Department of |
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