The Infrared Absorption Spectrum of Carbon Suboxide
dc.contributor.author | Lord, R. C. | en_US |
dc.contributor.author | Wright, Norman | en_US |
dc.date.accessioned | 2010-05-06T23:29:39Z | |
dc.date.available | 2010-05-06T23:29:39Z | |
dc.date.issued | 1937-08 | en_US |
dc.identifier.citation | Lord, R. C.; Wright, Norman (1937). "The Infrared Absorption Spectrum of Carbon Suboxide." The Journal of Chemical Physics 5(8): 642-649. <http://hdl.handle.net/2027.42/71281> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/71281 | |
dc.description.abstract | The infrared absorption spectrum of carbon suboxide vapor has been studied under low dispersion in the region from 2μ to 25μ. The vibrational bands observed may be satisfactorily accounted for on the basis of a linear symmetric structure for the carbon suboxide molecule, in agreement with evidence obtained from Raman spectra and from electron diffraction investigations. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 568662 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | The Infrared Absorption Spectrum of Carbon Suboxide | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Departments of Chemistry and Physics, University of Michigan, Ann Arbor, Michigan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/71281/2/JCPSA6-5-8-642-1.pdf | |
dc.identifier.doi | 10.1063/1.1750091 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | Brockway and Pauling, Proc. Nat. Acad. Sci. 19, 860 (1933). | en_US |
dc.identifier.citedreference | Boersch, Naturwiss. 22, 172 (1934); Wien Ber. 144 (IIb) 1 (1935). | en_US |
dc.identifier.citedreference | Badger and Barton, Proc. Nat. Acad. Sci. 20, 166 (1934). | en_US |
dc.identifier.citedreference | Thompson and Healey, Proc. Roy. Soc. (London) A157, 331 (1936). | en_US |
dc.identifier.citedreference | Engler and Kohlrausch, Zeits. f. Physik. Chemie B34, 214 (1936). | en_US |
dc.identifier.citedreference | H. M. Randall and J. Strong, Rev. Sci. Inst. 2, 585 (1931). | en_US |
dc.identifier.citedreference | F. A. Firestone, Rev. Sci. Inst. 3, 163 (1932). | en_US |
dc.identifier.citedreference | Hurd and Pilgrim, J. Am. Chem. Soc. 55, 757 (1933). | en_US |
dc.identifier.citedreference | E.g., reference 4, p. 332. | en_US |
dc.identifier.citedreference | Compare the acetylene vibrations ν4ν4 and ν5ν5 (Colby, Phys. Rev. 47, 388 (1935)) which are analogous to ν5,6ν5,6 and ν7ν7 in carbon suboxide. Difficulties with the calculation of the corresponding frequencies in benzene, ν11ν11 and ν10,ν10, have been pointed out by Kohlrausch, Zeits. f. Physik. Chemie B30, 313 (1935) and by Lord and Andrews, J. Phys. Chem. 41, 151 (1937). | en_US |
dc.identifier.citedreference | See Dennison, Rev. Mod. Phys. 3, 297 (1931). | en_US |
dc.identifier.citedreference | Barker and Wu, Phys. Rev. 45, 1 (1934). | en_US |
dc.identifier.citedreference | Cf. Dennison, reference 11, p. 296. | en_US |
dc.identifier.citedreference | Cf. the relatively high intensity of the overtones at 3610 and 3717 cm−13717cm−1 in CO2.CO2. This pair of bands constitutes a resonance doublet. | en_US |
dc.owningcollname | Physics, Department of |
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