Intermolecular multiple scattering of electrons. II. Observed effects for SF6
dc.contributor.author | Jin, Anding | en_US |
dc.contributor.author | Bartell, Lawrence S. | en_US |
dc.date.accessioned | 2010-05-06T23:32:46Z | |
dc.date.available | 2010-05-06T23:32:46Z | |
dc.date.issued | 1983-06-15 | en_US |
dc.identifier.citation | Jin, Anding; Bartell, Lawrence S. (1983). "Intermolecular multiple scattering of electrons. II. Observed effects for SF6." The Journal of Chemical Physics 78(12): 7165-7168. <http://hdl.handle.net/2027.42/71314> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/71314 | |
dc.description.abstract | A theory of intermolecular multiple scattering of electrons by vapor molecules is tested by comparing predicted effects with effects observed over a wide range of sample densities. It is found that the theory, which contains no adjustable constants and is based on small angle approximations, gives a good account of experimental observations. The degree to which experimental structure refinements are degraded by multiple scattering is also examined. It is found that derived internuclear distances are disturbed very little even when the mean number of scatterings per electron is as high as 2 and the interference features are washed out by a factor of 2. Apparent amplitudes of vibration are influenced more significantly but are still correctable with fair precision. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 309532 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Intermolecular multiple scattering of electrons. II. Observed effects for SF6 | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/71314/2/JCPSA6-78-12-7165-1.pdf | |
dc.identifier.doi | 10.1063/1.444757 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | L. S. Bartell, M. A. Kacner, and S. R. Goates, J. Chem. Phys. 75, 2730, 2736 (1981). | en_US |
dc.identifier.citedreference | S. R. Goates, Ph.D. thesis, University of Michigan, 1981. | en_US |
dc.identifier.citedreference | M. A. Kacner, Ph.D. thesis, University of Michigan, 1983. | en_US |
dc.identifier.citedreference | L. S. Bartell and A. Jin, J. Chem. Phys. 78, 7159 (1983). | en_US |
dc.identifier.citedreference | See AIP document No. PAPS JCPSA‐78‐7165‐9 for 9 pages of related materials including conditions under which the diffraction plates were taken, representative intensities and derived results. Order by PAPS number and journal reference from American Institute of Physics, Physics Auxiliary Publication Service, 335 E. 46 St., New York, NY 10017. The price is $1.50 for each microfiche (98 pages), or $5 for photocopies of up to 30 pages and $0.15 for each page over 30 pages. Airmail is additional. Make checks payable to American Institute of Physics. | en_US |
dc.identifier.citedreference | K. Ashkenas and F. S. Sherman, Rarified Gas Dynamics, Fourth Symposium, edited by J. M. de Leeuw (Academic, New York, 1966), Vol. II, p. 84. | en_US |
dc.identifier.citedreference | L. S. Bartell, in Physical Methods in Chemistry, 4th ed., edited by A. Weissberger and B. W. Rossiter (Interscience, New York, 1973). | en_US |
dc.identifier.citedreference | L. S. Bartell, J. Mol. Struct. 84, 117 (1982). | en_US |
dc.identifier.citedreference | K. L. Sellers, L. Schafer, and R. A. Bonham, J. Mol. Struct. 49, 125 (1978). | en_US |
dc.identifier.citedreference | C. Tavard, D. Nicoles, and M. Rouault, J. Chim. Phys. (Paris) 64, 540 (1967). | en_US |
dc.identifier.citedreference | See, for example, B. R. Miller and L. S. Bartell, J. Chem. Phys. 72, 800 (1980). | en_US |
dc.identifier.citedreference | L. S. Bartell, J. Appl. Phys. 31, 252 (1960). | en_US |
dc.identifier.citedreference | H. R. Foster, J. Appl. Phys. 41, 5344 (1970); L. S. Bartell and L. O. Brockway, 24, 656 (1953). | en_US |
dc.identifier.citedreference | P. Pulay, R. Mawhorter, D. A. Kohl, and M. Fink, J. Chem. Phys. (submitted); D. A. Kohl and L. S. Bartell, J. Chem. Phys. 51, 2891, 2896 (1969). | en_US |
dc.identifier.citedreference | At higher pressures systematic intensity residuals are observed that arise because the effects of multiple scattering in experimental data are not compensated for in the single scattering fitting theory. These residuals are significantly correlated in form and position with those caused by the redistribution of molecular electrons. | en_US |
dc.owningcollname | Physics, Department of |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.