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Heteronuclear isotropic mixing separated local field NMR spectroscopy
dc.contributor.authorDvinskikh, Sergey V.en_US
dc.contributor.authorYamamoto, Kazutoshien_US
dc.contributor.authorRamamoorthy, Ayyalusamyen_US
dc.date.accessioned2011-11-15T16:10:33Z
dc.date.available2011-11-15T16:10:33Z
dc.date.issued2006-07-21en_US
dc.identifier.citationDvinskikh, Sergey V.; Yamamoto, Kazutoshi; Ramamoorthy, Ayyalusamy (2006). "Heteronuclear isotropic mixing separated local field NMR spectroscopy." The Journal of Chemical Physics 125(3): 034507-034507-13. <http://hdl.handle.net/2027.42/87875>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/87875
dc.description.abstractThis paper presents a theoretical, numerical, and experimental study of a new class of separated local field (SLF) techniques. These techniques are based on the heteronuclear isotropic mixing leading to spin exchange via the local field (HIMSELF). It is shown that highly efficient and robust SLF experiments can be designed based on double channel windowless homonuclear decoupling sequences. Compared to rotating frame techniques based on Hartmann-Hahn cross polarization, the new approach is less susceptible to the frequency offset and chemical shift interaction and can be applied in the structural studies of macromolecules that are uniformly labeled with isotopes such as 13C13C and 15N15N. Furthermore, isotropic mixing sequences allow for transfer of any magnetization component of one nucleus to the corresponding component of its dipolar coupled partner. The performance of HIMSELF is studied by analysis of the average Hamiltonian and numerical simulation and is experimentally demonstrated on a single crystalline sample of a dipeptide and a liquid crystalline sample exhibiting motionally averaged dipolar couplings.en_US
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleHeteronuclear isotropic mixing separated local field NMR spectroscopyen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumBiophysics Research Division, University of Michigan, Ann Arbor, Michigan 48109-1055, Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, and Institute of Physics, St. Petersburg State University, 198504 St. Petersburg, Russiaen_US
dc.contributor.affiliationumBiophysics Research Division, University of Michigan, Ann Arbor, Michigan 48109-1055 and Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/87875/2/034507_1.pdf
dc.identifier.doi10.1063/1.2212939en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.owningcollnamePhysics, Department of


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