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Preparation of multitritiated arenes

dc.contributor.authorCacace, Fulvioen_US
dc.contributor.authorSperanza, Maurizioen_US
dc.contributor.authorWolf, Alfred P.en_US
dc.contributor.authorEhrenkaufer, Richard E.en_US
dc.date.accessioned2012-03-16T15:59:40Z
dc.date.available2012-03-16T15:59:40Z
dc.date.issued1982-08en_US
dc.identifier.citationCacace, Fulvio; Speranza, Maurizio; Wolf, Alfred P.; Ehrenkaufer, Richard (1982). "Preparation of multitritiated arenes." Journal of Labelled Compounds and Radiopharmaceuticals 19(8): 905-914. <http://hdl.handle.net/2027.42/90312>en_US
dc.identifier.issn0362-4803en_US
dc.identifier.issn1099-1344en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/90312
dc.description.abstractThe decay technique, currently applied to the study of ionic processes in gaseous and liquid systems, requires multitritiated precursors to generate labeled daughter ions. The preparation of three such precursors, namely C 6 3 H x H 6−x , C 6 3 H x H 5−x CH 3 , and C 6 H 5 C 3 H 3−x is described. The ring–labeled precursors were obtained from the cyclization of C 2 3 H 2 , and respectively of a C 2 3 H 2 /propyne mixture, carried out at 25°C over a K 2 CrO 4 –promoted silica–alumina catalyst. The side–chain tritiated toluene was prepared by allowing 3 H 2 O and benzotrichloride to react over a Zn mirror at 200°C. Details of the procedures employed for the radiometric and the isotopic analysis of the multilabeled products are reported.en_US
dc.publisherJohn Wiley & Sons, Ltd.en_US
dc.titlePreparation of multitritiated arenesen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelRadiologyen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumUniversity of Michigan Hospital, Ann Arbor, Michigan 48109en_US
dc.contributor.affiliationotherChemistry Department, Brookhaven National Laboratory, Upton, N.Y. 11973en_US
dc.contributor.affiliationotherIstituto di Chimica Nucleare del C.N.R., C.P. 10, 00016 Monterotondo Stazione (Rome), Italyen_US
dc.contributor.affiliationotherUniversita di Roma, 00100 Rome, Italyen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/90312/1/2580190803_ftp.pdf
dc.identifier.doi10.1002/jlcr.2580190803en_US
dc.identifier.sourceJournal of Labelled Compounds and Radiopharmaceuticalsen_US
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dc.identifier.citedreferenceAn experimental confirmation of this view was obtained observing the rapid formation of a cuprene film onto the walls of a pyrex vial containing ca. 10 Ci of C 2 3 H 2 allowed to stand at room temperature and in the dark for a few hours.en_US
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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