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Reexamination of the Direct Electrochemical Reduction of S ‐Nitrosothiols
dc.contributor.authorPeng, Boen_US
dc.contributor.authorMeyerhoff, Mark E.en_US
dc.date.accessioned2013-05-02T19:34:59Z
dc.date.available2014-05-23T15:04:20Zen_US
dc.date.issued2013-04en_US
dc.identifier.citationPeng, Bo; Meyerhoff, Mark E. (2013). "Reexamination of the Direct Electrochemical Reduction of S ‐Nitrosothiols." Electroanalysis 25(4): 914-921. <http://hdl.handle.net/2027.42/97455>en_US
dc.identifier.issn1040-0397en_US
dc.identifier.issn1521-4109en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/97455
dc.description.abstractWe report here on the electrochemical reduction of S ‐nitrosothiol species (RSNO). Nitric oxide (NO) is the reported common product from electrochemically reduced RSNOs at physiological pH. However, studies here at pH 7.4 show that during the reduction of RSNOs (−0.6 V to −0.9 V, vs. Ag/AgCl), no significant amount of NO is detected. Gas analysis suggests RSNO are reduced to nitrous oxide (N 2 O) at pH 7.4 and can only be converted back to NO at more oxidizing voltages. Interestingly, at pH 4.0, a direct one‐electron reduction of RSNOs appears to occur and generates significant amounts of NO from RSNO species.en_US
dc.publisherWILEY‐VCH Verlagen_US
dc.subject.otherNitric Oxideen_US
dc.subject.otherS ‐Nitrosothiolsen_US
dc.subject.otherNitrous Oxideen_US
dc.subject.otherElectrochemical Reductionen_US
dc.titleReexamination of the Direct Electrochemical Reduction of S ‐Nitrosothiolsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, 930 North University Ave., Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, 930 North University Ave., Ann Arbor, MI 48109, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/97455/1/elan_201200445_sm_miscellaneous_information.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/97455/2/914_ftp.pdf
dc.identifier.doi10.1002/elan.201200445en_US
dc.identifier.sourceElectroanalysisen_US
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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