Decoupled Control of Carbon Nanotube Forest Density and Diameter by Continuous‐Feed Convective Assembly of Catalyst Particles
dc.contributor.author | Polsen, Erik S. | en_US |
dc.contributor.author | Bedewy, Mostafa | en_US |
dc.contributor.author | Hart, A. John | en_US |
dc.date.accessioned | 2013-09-04T17:18:25Z | |
dc.date.available | 2014-10-06T19:17:41Z | en_US |
dc.date.issued | 2013-08-12 | en_US |
dc.identifier.citation | Polsen, Erik S.; Bedewy, Mostafa; Hart, A. John (2013). "Decoupled Control of Carbon Nanotube Forest Density and Diameter by Continuous‐Feed Convective Assembly of Catalyst Particles." Small 9(15): 2564-2575. <http://hdl.handle.net/2027.42/99619> | en_US |
dc.identifier.issn | 1613-6810 | en_US |
dc.identifier.issn | 1613-6829 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/99619 | |
dc.description.abstract | The widespread potential application of vertically aligned carbon nanotube (CNT) forests have stimulated recent work on large‐area chemical vapor deposition growth methods, but improved control of the catalyst particles is needed to overcome limitations to the monodispersity and packing density of the CNTs. In particular, traditional thin‐film deposition methods are not ideal due to their vacuum requirements, and due to limitations in particle uniformity and density imposed by the thin‐film dewetting process. Here, a continuous‐feed convective self‐assembly process for manufacturing uniform mono‐ and multi‐layers of catalyst particles for CNT growth is presented. Particles are deposited from a solution of commercially available iron oxide nanoparticles, by pinning the meniscus between a blade edge and the substrate. The substrate is translated at constant velocity under the blade so the meniscus and contact angle remain fixed as the particles are deposited on the substrate. Based on design of the particle solution and tuning of the assembly parameters, a priori control of CNT diameter and packing density is demonstrated. Quantitative relationships are established between the catalyst size and density, and the CNT morphology and density. The roll‐to‐roll compatibility of this method, along with initial results achieved on copper foils, suggest promise for scale‐up of CNT forest manufacturing at commercially relevant throughput. Continuous‐feed evaporative self‐assembly is used to create nanoparticle arrays for carbon nanotube (CNT) film growth. This versatile method enables specification of the CNT film morphology, and wide‐range tuning of the diameter and density of CNT forests. The present results exceed the performance limits of thin‐film catalyst dewetting, and the process is compatible with roll‐to‐roll manufacturing on flexible substrates. | en_US |
dc.publisher | WILEY‐VCH Verlag | en_US |
dc.subject.other | Catalysis | en_US |
dc.subject.other | Film Formation | en_US |
dc.subject.other | Carbon Nanotubes | en_US |
dc.subject.other | Nanoparticles | en_US |
dc.subject.other | Self‐Assembly | en_US |
dc.title | Decoupled Control of Carbon Nanotube Forest Density and Diameter by Continuous‐Feed Convective Assembly of Catalyst Particles | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Mechanosynthesis Group, Department of Mechanical Engineering, University of Michigan, 2350 Hayward St. Ann Arbor, MI 48109, USA | en_US |
dc.contributor.affiliationum | Mechanosynthesis Group, Department of Mechanical Engineering, University of Michigan, 2350 Hayward St. Ann Arbor, MI 48109, USA. | en_US |
dc.identifier.pmid | 23418098 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/99619/1/2564_ftp.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/99619/2/smll_201202878_sm_suppl.pdf | |
dc.identifier.doi | 10.1002/smll.201202878 | en_US |
dc.identifier.source | Small | en_US |
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dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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