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Desymmetrization of meso ‐2,5‐Diallylpyrrolidinyl Ureas through Asymmetric Palladium‐Catalyzed Carboamination: Stereocontrolled Synthesis of Bicyclic Ureas
dc.contributor.authorBabij, Nicholas R.en_US
dc.contributor.authorWolfe, John P.en_US
dc.date.accessioned2013-09-04T17:18:28Z
dc.date.available2014-10-06T19:17:42Zen_US
dc.date.issued2013-08-26en_US
dc.identifier.citationBabij, Nicholas R.; Wolfe, John P. (2013). "Desymmetrization of meso ‐2,5‐Diallylpyrrolidinyl Ureas through Asymmetric Palladium‐Catalyzed Carboamination: Stereocontrolled Synthesis of Bicyclic Ureas ." Angewandte Chemie 125(35): 9417-9420. <http://hdl.handle.net/2027.42/99626>en_US
dc.identifier.issn0044-8249en_US
dc.identifier.issn1521-3757en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/99626
dc.publisherWILEY‐VCH Verlagen_US
dc.subject.otherHeterocyclenen_US
dc.subject.otherPalladiumen_US
dc.subject.otherAlkaloideen_US
dc.subject.otherAsymmetrische Katalyseen_US
dc.subject.otherDesymmetrisierungen_US
dc.titleDesymmetrization of meso ‐2,5‐Diallylpyrrolidinyl Ureas through Asymmetric Palladium‐Catalyzed Carboamination: Stereocontrolled Synthesis of Bicyclic Ureasen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109‐1055 (USA)en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109‐1055 (USA)en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/99626/1/9417_ftp.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/99626/2/ange_201302720_sm_miscellaneous_information.pdf
dc.identifier.doi10.1002/ange.201302720en_US
dc.identifier.sourceAngewandte Chemieen_US
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dc.identifier.citedreferenceThe substrate required for the preparation of (+)‐merobatzelladine B contained a functionalized side chain bearing a stereocenter, and the synthesis of this substrate required nine steps. Synthesis of an enantiopure substrate 5 (R=CH 2 CHC(H)TMS) required seven steps. See the Supporting information for details on the preparation of this latter compound, which was used to assign absolute stereochemistry of products 8 generated in catalytic reactions.en_US
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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