CO hydrogenation over alumina-supported sulfide cluster catalysts
dc.contributor.author | Thompson, Levi T. | en_US |
dc.contributor.author | Schwank, Johannes W. | en_US |
dc.contributor.author | Curtis, M. David | en_US |
dc.date.accessioned | 2006-04-28T15:46:05Z | |
dc.date.available | 2006-04-28T15:46:05Z | |
dc.date.issued | 1989-01 | en_US |
dc.identifier.citation | Thompson, Levi T.; Schwank, Johannes; Curtis, M. David (1989)."CO hydrogenation over alumina-supported sulfide cluster catalysts." AIChE Journal 35(1): 109-119. <http://hdl.handle.net/2027.42/37405> | en_US |
dc.identifier.issn | 0001-1541 | en_US |
dc.identifier.issn | 1547-5905 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/37405 | |
dc.description.abstract | Bimetallic Mo-Fe and Mo-Co sulfide clusters were anchored on Al 2 O 3 and used for CO hydrogenation. In addition to methane, significant amounts of dimethyl ether were produced. The reaction orders obtained from power rate laws for methanation indicated that the surfaces of the catalytic ensembles were not completely saturated by CO, in contrast to the observations for most conventional CO hydrogenation catalysts. A kinetic analysis and parameter estimation was performed to identify the rate-determining step for methanation. A catalytic cycle was postulated that could account not only for the formation of methane and higher hydrocarbons, but also for dimethyl ether as a primary product. | en_US |
dc.format.extent | 1219760 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | American Institute of Chemical Engineers | en_US |
dc.publisher | Wiley Periodiocals, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Chemical Engineering | en_US |
dc.title | CO hydrogenation over alumina-supported sulfide cluster catalysts | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48 109 | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48 109 ; Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48 109 | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/37405/1/690350112_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/aic.690350112 | en_US |
dc.identifier.source | AIChE Journal | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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