Now showing items 31-40 of 248
Fugacity coefficients for free radicals in dense fluids: HO 2 in supercritical water
(American Institute of Chemical EngineersWiley Periodiocals, Inc., 1997-05)
The fugacity coefficients of the hydroperoxyl radical in supercritical water are estimated through molecular simulations. A potential function for the radical is first derived from ab initio self-consistent field molecular ...
Dynamics of growth of silica particles from ammonia-catalyzed hydrolysis of tetra-ethyl-orthosilicate
(Elsevier, 1988-07)
The NH3-catalyzed formation of colloidal silica particles from tetra-ethyl-orthosilicate (TEOS) in methanol and ethanol is studied by means of light scattering and Raman spectroscopy. We find that the growth is characterized ...
Comparison of rigid and flexible simple point charge water models at supercritical conditions
(John Wiley & Sons, Inc., 1996-11-30)
This study investigates the differences between the predictions of various properties of rigid and flexible simple point charge water models at supercritical conditions. Molecular dynamics simulations were conducted for ...
Model for the reaction-rate-limited dissolution of solids with Etch-rate heterogeneities
(American Institute of Chemical EngineersWiley Periodiocals, Inc., 1996-09)
The coalescence of isotropic etch pits observed in the dissolution of semiconductor substrates is studied using a discrete model for the evolution of the surface under reaction-rate-limited conditions. The model discretizes ...
Acidization--IV : Experimental correlations and techniques for the acidization of sandstone cores
(Elsevier, 1976)
The experimental variables that affect the acidization of sandstone cores in a permeameter are discussed. It was found that as HCl/HF acid mixtures are injected into porous sandstone cores a reaction front between selective ...
Annealing effects of polymers and their underlying molecular mechanisms
(Elsevier, 1976-04)
This paper indicates that changes in chain mobility, heat capacity, WAXS crystallinity, SAXS long period, SAXS peak intensity, specific volume and morphology as a function of increasing temperature, occur in three fairly ...
Chemical permeabilization and in situ removal of daidzein from biologically viable soybean (Glycine max) seeds
(Kluwer Academic Publishers; Chapman and Hall ; Springer Science+Business Media, 1998-09)
After 24 h of chemical permeabilization with 20% (v/v) methanol at 25 °C, the amount of daidzein released from soybean seeds is 15 to 20% of the amount (0.0423 ± 0.0045 mg/g seed dry wt) obtained by physical grinding. With ...