Magnetic N‐Enriched Fe3C/Graphitic Carbon instead of Pt as an Electrocatalyst for the Oxygen Reduction Reaction
dc.contributor.author | Wang, Xiaobai | |
dc.contributor.author | Zhang, Peng | |
dc.contributor.author | Wang, Wei | |
dc.contributor.author | Lei, Xiang | |
dc.contributor.author | Yang, Hua | |
dc.date.accessioned | 2017-06-16T20:10:52Z | |
dc.date.available | 2017-06-16T20:10:52Z | |
dc.date.issued | 2016-03-24 | |
dc.identifier.citation | Wang, Xiaobai; Zhang, Peng; Wang, Wei; Lei, Xiang; Yang, Hua (2016). "Magnetic N‐Enriched Fe3C/Graphitic Carbon instead of Pt as an Electrocatalyst for the Oxygen Reduction Reaction." Chemistry – A European Journal 22(14): 4863-4869. | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.issn | 1521-3765 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/137352 | |
dc.description.abstract | A series of Fe3C/C‐Nx nanoparticles (NPs) with different nitrogen content are prepared by a simple one‐pot route. In the synthetic procedure, aniline and acetonitrile are simultaneously used as the carbon and nitrogen source. The effect of calcination temperature on the structural and functional properties of the materials is investigated. Magnetic measurement shows that the sample prepared at 800 °C (Fe3C/C‐N800 NPs) possesses the highest Ms value of 77.2 emu g−1. On testing as oxygen reduction reaction (ORR) catalysts, the sample prepared at 750 °C (Fe3C/C‐N750 NPs) shows the best ORR performance among the series, with a more positive onset potential (+0.99 V vs. RHE), higher selectivity (number of electron transfer n≈3.93), longer durability, and stronger tolerance against methanol crossover than commercial Pt/C catalysts in a 0.1 m KOH solution. Moreover, in acidic solution, the excellent ORR activity and stability are also exhibited.Magnetic nanomaterials: A series of Fe3C/C‐Nx nanoparticles (NPs) with different nitrogen content are prepared by a simple one‐pot route (see figure). The materials exhibit excellent magnetic properties and oxygen reduction reaction (ORR) activities. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | magnetic properties | |
dc.subject.other | fuel cells | |
dc.subject.other | nanomaterials | |
dc.subject.other | nitrogen | |
dc.subject.other | reduction | |
dc.title | Magnetic N‐Enriched Fe3C/Graphitic Carbon instead of Pt as an Electrocatalyst for the Oxygen Reduction Reaction | |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Chemistry | |
dc.subject.hlbtoplevel | Science | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/137352/1/chem201505138_am.pdf | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/137352/2/chem201505138-sup-0001-misc_information.pdf | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/137352/3/chem201505138.pdf | |
dc.identifier.doi | 10.1002/chem.201505138 | |
dc.identifier.source | Chemistry – A European Journal | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | ||
dc.identifier.citedreference | Y. Hu, J. O. Jensen, W. Zhang, L. N. Cleemann, W. Xing, N. J. Bjerrum, Q. Li, Angew. Chem. Int. Ed. 2014, 53, 3675 – 3679; Angew. Chem. 2014, 126, 3749 – 3753; | |
dc.identifier.citedreference | G. Zhong, H. Wang, H. Yu, F. Peng, J. Power Sources 2015, 286, 495 – 503. | |
dc.identifier.citedreference | S. Gao, K. Geng, H. Liu, X. Wei, M. Zhang, P. Wang, J. Wang, Energy Environ. Sci. 2015, 8, 221 – 229. | |
dc.identifier.citedreference | G. Liu, X. Li, J.-W. Lee, B. N. Popov, Catal. Sci. Technol. 2011, 1, 207 – 217; | |
dc.identifier.citedreference | X. Zhou, Z. Yang, H. Nie, Z. Yao, L. Zhang, S. Huang, J. Power Sources 2011, 196, 9970 – 9974. | |
dc.identifier.citedreference | F. Tuinstra, J. L. Koenig, J. Chem. Phys. 1970, 53, 1126 – 1130. | |
dc.identifier.citedreference | X. Wang, P. Zhang, J. Gao, X. Chen, H. Yang, Dyes Pigments 2015, 112, 305 – 310. | |
dc.identifier.citedreference | X. Wang, P. Zhang, W. Wang, X. Lei, B. Zou, H. Yang, RSC Adv. 2015, 5, 27857 – 27861. | |
dc.identifier.citedreference | J. W. Chevalier, J. Y. Bergeron, L. H. Dao, Macromolecules 1992, 25, 3325 – 3331. | |
dc.identifier.citedreference | M. I. Boyer, S. Quillard, E. Rebourt, G. Louarn, J. P. Buisson, A. Monkman, S. Lefrant, J. Phys. Chem. B 1998, 102, 7382 – 7392. | |
dc.identifier.citedreference | Z. Schnepp, S. C. Wimbush, M. Antonietti, C. Giordano, Chem. Mater. 2010, 22, 5340 – 5344. | |
dc.identifier.citedreference | W.-J. Liu, K. Tian, Y.-R. He, H. Jiang, H.-Q. Yu, Environ. Sci. Technol. 2014, 48, 13951 – 13959. | |
dc.identifier.citedreference | W. Yang, X. Yue, X. Liu, J. Zhai, J. Jia, Nanoscale 2015, 7, 11956 – 11961. | |
dc.identifier.citedreference | W. Niu, L. Li, X. Liu, N. Wang, J. Liu, W. Zhou, Z. Tang, S. Chen, J. Am. Chem. Soc. 2015, 137, 5555 – 5562. | |
dc.identifier.citedreference | P. Chen, L.-K. Wang, G. Wang, M.-R. Gao, J. Ge, W.-J. Yuan, Y.-H. Shen, A.-J. Xie, S.-H. Yu, Energy Environ. Sci. 2014, 7, 4095 – 4103. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | X. Zheng, J. Deng, N. Wang, D. Deng, W. H. Zhang, X. Bao, C. Li, Angew. Chem. Int. Ed. 2014, 53, 7023 – 7027; Angew. Chem. 2014, 126, 7143 – 7147; | |
dc.identifier.citedreference | H. T. Chung, J. H. Won, P. Zelenay, Nat. Commun. 2013, 4, 1922. | |
dc.identifier.citedreference | Y. Hu, J. O. Jensen, W. Zhang, Y. Huang, L. N. Cleemann, W. Xing, N. J. Bjerrum, Q. Li, ChemSusChem 2014, 7, 2099 – 2103. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | M. K. Debe, Nature 2012, 486, 43 – 51; | |
dc.identifier.citedreference | B. C. Steele, A. Heinzel, Nature 2001, 414, 345 – 352. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | Y.-J. Wang, N. Zhao, B. Fang, H. Li, X. T. Bi, H. Wang, Chem. Rev. 2015, 115, 3433 – 3467; | |
dc.identifier.citedreference | A. Chen, P. Holt-Hindle, Chem. Rev. 2010, 110, 3767 – 3804; | |
dc.identifier.citedreference | S. E. Kleijn, S. Lai, M. Koper, P. R. Unwin, Angew. Chem. Int. Ed. 2014, 53, 3558 – 3586; Angew. Chem. 2014, 126, 3630 – 3660; | |
dc.identifier.citedreference | C. Wang, H. Daimon, Y. Lee, J. Kim, S. Sun, J. Am. Chem. Soc. 2007, 129, 6974 – 6975; | |
dc.identifier.citedreference | S. Guo, S. Zhang, S. Sun, Angew. Chem. Int. Ed. 2013, 52, 8526 – 8544; Angew. Chem. 2013, 125, 8686 – 8705; | |
dc.identifier.citedreference | S. Sun, Z. Jusys, R. J. Behm, J. Power Sources 2013, 231, 122 – 133; | |
dc.identifier.citedreference | X. Zhou, Y. Gan, J. Du, D. Tian, R. Zhang, C. Yang, Z. Dai, J. Power Sources 2013, 232, 310 – 322. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | X. Zhao, S. Chen, Z. Fang, J. Ding, W. Sang, Y. Wang, J. Zhao, Z. Peng, J. Zeng, J. Am. Chem. Soc. 2015, 137, 2804 – 2807; | |
dc.identifier.citedreference | W. Wang, Y. Zhao, Y. Ding, Nanoscale 2015, 7, 11934 – 11939. | |
dc.identifier.citedreference | W. Xia, J. Masa, M. Bron, W. Schuhmann, M. Muhler, Electrochem. Commun. 2011, 13, 593 – 596. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | F. Jaouen, E. Proietti, M. Lefèvre, R. Chenitz, J.-P. Dodelet, G. Wu, H. T. Chung, C. M. Johnston, P. Zelenay, Energy Environ. Sci. 2011, 4, 114 – 130; | |
dc.identifier.citedreference | Z. Chen, D. Higgins, A. Yu, L. Zhang, J. Zhang, Energy Environ. Sci. 2011, 4, 3167 – 3192; | |
dc.identifier.citedreference | H. Yuan, Y. Hou, Z. Wen, X. Guo, J. Chen, Z. He, ACS Appl. Mater. Interfaces 2015, 7, 18672 – 18678. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | G. Wu, K. L. More, C. M. Johnston, P. Zelenay, Science 2011, 332, 443 – 447; | |
dc.identifier.citedreference | Y. Hu, J. O. Jensen, W. Zhang, S. Martin, R. Chenitz, C. Pan, W. Xing, N. J. Bjerrum, Q. Li, J. Mater. Chem. A 2015, 3, 1752 – 1760; | |
dc.identifier.citedreference | J. Wang, G. Wang, S. Miao, X. Jiang, J. Li, X. Bao, Carbon 2014, 75, 381 – 389; | |
dc.identifier.citedreference | S. Chao, Q. Cui, K. Wang, Z. Bai, L. Yang, J. Qiao, J. Power Sources 2015, 288, 128 – 135; | |
dc.identifier.citedreference | A. Muthukrishnan, Y. Nabae, C. W. Chang, T. Okajima, T. Ohsaka, Catal. Sci. Technol. 2015, 5, 1764 – 1774. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | N. Daems, X. Sheng, I. F. J. Vankelecom, P. P. Pescarmona, J. Mater. Chem. A 2014, 2, 4085 – 4110; | |
dc.identifier.citedreference | Q. Li, H. Pan, D. Higgins, R. Cao, G. Zhang, H. Lv, K. Wu, J. Cho, G. Wu, Small 2015, 11, 1443 – 1452; | |
dc.identifier.citedreference | W.-B. Luo, S.-L. Chou, J.-Z. Wang, Y.-C. Zhai, H.-K. Liu, Small 2015, 11, 2817 – 2824; | |
dc.identifier.citedreference | A. Zehtab Yazdi, K. Chizari, A. S. Jalilov, J. Tour, U. Sundararaj, ACS Nano 2015, 9, 5833 – 5845. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | M. Kim, D.-H. Nam, H.-Y. Park, C. Kwon, K. Eom, S. Yoo, J. Jang, H.-J. Kim, E. Cho, H. Kwon, J. Mater. Chem. A 2015, 3, 14284 – 14290; | |
dc.identifier.citedreference | Z. Lu, G. Xu, C. He, T. Wang, L. Yang, Z. Yang, D. Ma, Carbon 2015, 84, 500 – 508; | |
dc.identifier.citedreference | M. Li, X. Bo, Y. Zhang, C. Han, A. Nsabimana, L. Guo, J. Mater. Chem. A 2014, 2, 11672 – 11682. | |
dc.identifier.citedreference | Y. Hou, T. Huang, Z. Wen, S. Mao, S. Cui, J. Chen, Adv. Energy Mater. 2014, 4, 1400337. | |
dc.identifier.citedreference | W. Yang, X. Liu, X. Yue, J. Jia, S. Guo, J. Am. Chem. Soc. 2015, 137, 1436 – 1439. | |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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