Now showing items 81-90 of 804
A convenient synthesis of substituted [gamma]-pyrones
(Elsevier, 1980)
An efficient and general synthetic method for various 2-mono- and 2,6-disubstituted [gamma]-pyrones has been developed. This utilizes the -acylation (70-85%) of [beta]-methoxy-[alpha],[beta]-enone lithium enolates by acid ...
Cyclic siloxanes and silsesquioxanes as cores and frameworks for the construction of ferrocenyl dendrimers and polymers
(John Wiley & Sons, Ltd., 1999-04)
Starting from 1,3,5,7-tetramethylcyclotetrasiloxane as core, novel ferrocenyl silicon-containing dendrimers have been constructed up to the third generation, which contains 16 peripheral ferrocene moieties. As precursors ...
Comparative proteomic study of two closely related ovarian endometrioid adenocarcinoma cell lines using cIEF fractionation and pathway analysis
(WILEY-VCH Verlag, 2009-04)
The proteomic profiles from two distinct ovarian endometrioid tumor-derived cell lines, (MDAH-2774 and TOV-112D) each with different morphological characteristics and genetic mutations, have been studied. Characterization ...
Thermodynamics of alkali alkanoates VII. Heat capacity and thermodynamic functions of potassium acetate from 4 to 585 K
(Elsevier, 1990-01)
The heat capacity of potassium acetate was measured by equilibrium adiabatic calorimetry from near 4 K up to 350 K and by d.s.c. from 325 K through melting (solid to isotropic liquid) to 585 K. No transition or anomaly was ...
Trimethylstannyl-2,4-cycloheptadiene: A fluxional molecule
(Elsevier, 1972-05-16)
Trimethylstannyl-2,4-cycloheptadiene (II) was synthesized and shown to be fluxional on the NMR time scale. The activation energy for the [1,5] trimethyltin migration is estimated to be ca. 18 kcal/mole. This value is ...
Quantitative Determination of High Charge Density Polyanion Contaminants in Biomedical Heparin Preparations Using Potentiometric Polyanion Sensors
(WILEY-VCH Verlag, 2010-01)
Quantification of oversulfated chondroitin sulfate (OSCS) in biomedical heparin preparations is achieved using a recently described potentiometric polyanion sensor-based approach operated in a kinetic mode of analysis. ...
Supercritical fluid jet expansions of polar aromatic carboxylic acids using simple derivatization with detection by resonant two-photon ionization
(Elsevier, 1988)
In this work simple derivatization is used as a means of enhancing the solubility of polar aromatic carboxylic acids in supercritical CO2 and N2O. The supercritical fluid is then expanded from 200 atm and 40[deg]C through ...
MOCVD of rhodium, palladium and platinum complexes on fluidized divided substrates: Novel process for one-step preparation of noble-metal catalysts
(John Wiley & Sons, Ltd., 1998-03)
A new one-step method, entitled fluidized-bed metal-organic chemical vapor deposition (FBMOCVD) of preparing highly dispersed metal-supported catalysts is reported. The following complexes were studied and used as CVD ...
Synthesis of the Tetraketide Lactones from the Pikromycin Biosynthetic Pathway
(WILEY-VCH Verlag, 2007-07)
Synthesis of tetraketide lactones 2 and 3 , which are likely to be produced by a model pikromycin polyketide synthase (PKS), has been investigated. The tetraketide lactones with six-membered rings, 2a and 2b , were ...