Now showing items 181-187 of 187
Vibrational analysis of crystalline diketopiperazine--I. Raman and i.r. spectra
(Elsevier, 1984)
Raman and i.r. spectra have been obtained of diketopiperazine and five of its isotopic derivatives: (CONDCH2)2, (CONHCD2)2, (CONDCD2)2, (13CONHCH2)2 and (13CONDCH2)2. In addition to solution spectra and powder spectra at ...
Synthesis and rearrangements of ortho-selenonium phenoxides
(Elsevier, 1987)
A new class of selenonium zwitterions is prepared from the ortho- substitution of phenols with diphenylselenium bis(trifluoroacetate) 1. The zwitterions undergo a novel thermal rearrangement to produce diaryl ethers.
A general procedure for mild and rapid reduction of aliphatic and aromatic nitro compounds using ammonium formate as a catalytic hydrogen transfer agent
(Elsevier, 1984)
Various aliphatic and aromatic nitro compounds were selectively and rapidly reduced to their corresponding amino derivatives in very good yield using anhydrous ammonium formate as a catalytic hydrogen transfer agent.
A practical large scale chemical synthesis of chiral glycines
(Elsevier, 1988)
(R)- and (S)-[2-2H]glycine of high chiral purity were synthesized in large quantities in [approximate] 40% overall yield from readily available starting materials via a totally chemical procedure. Reduction of either ...
Thermodynamics of copper sulfides I. Heat capacity and thermodynamic properties of copper(I) sulfide, Cu2S, from 5 to 950 K
(Elsevier, 1987-11)
The heat capacity of Cu2S from 5 to 950 K was determined by adiabatic-shield calorimetry and the thermodynamic properties were evaluated. Transitions occur at 376 and about 710 K with [Delta]trsSm = (1.240+/-0.006)R and ...
Are cationic [eta]3-allyl complexes general precursors to metallacyclobutanes? Synthesis and structure of [mu]-chloro-bis[([eta]3-allyl)-2,2'-bipyridyldicarbonylmolybdenum(II)] tetrafluoroborate
(Elsevier, 1984-08-28)
Silver tetrafluoroborate reacts with Cl(bipy)(CO)2([eta]3-C3H5)Mo in CH2Cl2 to give the dimeric cation, ([mu]-Cl)[(bipy)(CO)2([eta]3-C3H5)Mo]2+, isolated as the crystalline BF4- salt with CH2Cl2 of solvation (5). Complex ...
1,4-Additions of the highly functionalized copper reagents RCu(CN)ZnI [middle dot] 2 BFP3 to trisubstituted enones. A new BF3 promoted cyclization reaction
(Elsevier, 1988)
The new copper reagents RCu(CN)Zn I [middle dot] 2 BF3 1 containing various functional groups like esters, cyanides, chlorides or enoates react with [beta], [beta]'- disubstituted enones to afford the Michael adducts 4-7 ...