Polyion Detection via All‐solid‐contact Paper‐based Polyion‐sensitive Polymeric Membrane Electrodes
dc.contributor.author | Ferguson, Stephen A. | |
dc.contributor.author | Meyerhoff, Mark E. | |
dc.date.accessioned | 2019-09-30T15:30:00Z | |
dc.date.available | WITHHELD_12_MONTHS | |
dc.date.available | 2019-09-30T15:30:00Z | |
dc.date.issued | 2019-08 | |
dc.identifier.citation | Ferguson, Stephen A.; Meyerhoff, Mark E. (2019). "Polyion Detection via All‐solid‐contact Paper‐based Polyion‐sensitive Polymeric Membrane Electrodes." Electroanalysis 31(8): 1433-1437. | |
dc.identifier.issn | 1040-0397 | |
dc.identifier.issn | 1521-4109 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/151253 | |
dc.description.abstract | The first all‐solid‐contact paper‐based single‐use polyion‐sensitive ion‐selective electrodes (ISEs) are described. These polyion‐sensitive ISEs are fabricated using cellulose filter paper coated with a carbon ink conductive layer. A polyanion sensing membrane is cast on a section of the coated paper and the sensor is insulated, resulting in a disposable, single‐use device. Various polyanions are shown to yield large negative potentiometric responses when using these disposable devices for direct polyanion detection. These new sensors are further demonstrated to be useful in indirect polycation detection when polycations (i. e., polyquaterniums (PQs)) are titrated with polyanionic dextran sulfate (DS). Titrations monitored using these paper‐based, all‐solid‐contact devices yield endpoints proportional to the given PQ concentration present in the test sample. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | ion-selective electrodes | |
dc.subject.other | polyion sensors | |
dc.subject.other | paper-based devices | |
dc.subject.other | titration | |
dc.subject.other | polyquaternium species | |
dc.title | Polyion Detection via All‐solid‐contact Paper‐based Polyion‐sensitive Polymeric Membrane Electrodes | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Biological Chemistry | |
dc.subject.hlbsecondlevel | Chemical Engineering | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbsecondlevel | Chemistry | |
dc.subject.hlbtoplevel | Science | |
dc.subject.hlbtoplevel | Engineering | |
dc.subject.hlbtoplevel | Health Sciences | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/151253/1/elan201900155.pdf | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/151253/2/elan201900155_am.pdf | |
dc.identifier.doi | 10.1002/elan.201900155 | |
dc.identifier.source | Electroanalysis | |
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dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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