Directed biosynthesis of unnatural alkaloids in Dolichothele sphaerica
dc.contributor.author | Rosenberg, Harry | en_US |
dc.contributor.author | Stohs, Sidney J. | en_US |
dc.contributor.author | Paul, Ara G. | en_US |
dc.date.accessioned | 2006-04-07T16:47:00Z | |
dc.date.available | 2006-04-07T16:47:00Z | |
dc.date.issued | 1974-05 | en_US |
dc.identifier.citation | Rosenberg, Harry, Stohs, Sidney J., Paul, Ara G. (1974/05)."Directed biosynthesis of unnatural alkaloids in Dolichothele sphaerica." Phytochemistry 13(5): 823-828. <http://hdl.handle.net/2027.42/22364> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TH7-42WH5V6-8/2/2900082844362cbd528270faf417953f | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/22364 | |
dc.description.abstract | Using appropriate precursors, the two unnatural alkaloids 4(5)-[N-isocaproylaminomethyl]imidazole and 3-[2-N-isovalerylaminoethyl]pyrazole were produced by Dolichothele sphaerica. The former compound represents an unnatural alkaloid formed by the simultaneous introduction of two unnatural precursors, namely isocaproic acid and 4(5)-aminomethylimidazole. The latter compound represents an aberrant alkaloid formed by the introduction of a precursor of different heterocyclic entity, 3-aminoethylpyrazole. | en_US |
dc.format.extent | 425178 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Directed biosynthesis of unnatural alkaloids in Dolichothele sphaerica | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Molecular, Cellular and Developmental Biology | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | College of Pharmacy, The University of Michigan, Ann Arbor, MI 48104, U.S.A. | en_US |
dc.contributor.affiliationother | College of Pharmacy, The University of Nebraska, Lincoln, NE 68508, U.S.A. | en_US |
dc.contributor.affiliationother | College of Pharmacy, The University of Nebraska, Lincoln, NE 68508, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/22364/1/0000811.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/S0031-9422(00)91146-4 | en_US |
dc.identifier.source | Phytochemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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