The chlorine nuclear quadrupole coupling tensor in chlorotrifluoroethylene
dc.contributor.author | Hillig, Kurt W. II | en_US |
dc.contributor.author | Bittner, Eric R. | en_US |
dc.contributor.author | Kuczkowski, Robert L. | en_US |
dc.contributor.author | Lewis-Bevan, W. | en_US |
dc.contributor.author | Gerry, M. C. L. | en_US |
dc.date.accessioned | 2006-04-07T20:31:51Z | |
dc.date.available | 2006-04-07T20:31:51Z | |
dc.date.issued | 1988-12 | en_US |
dc.identifier.citation | Hillig, II, K. W., Bittner, E. R., Kuczkowski, R. L., Lewis-Bevan, W., Gerry, M. C. L. (1988/12)."The chlorine nuclear quadrupole coupling tensor in chlorotrifluoroethylene." Journal of Molecular Spectroscopy 132(2): 369-379. <http://hdl.handle.net/2027.42/27550> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WK8-4CRHFC9-G2/2/bd63269aed895b4fe5264bfce76d4c6b | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/27550 | |
dc.description.abstract | The 273 hyperfine components from 56 rotational transitions of chlorotrifluoroethylene were measured with a Fourier transform microwave spectrometer. A global least-squares fit was made to the rotational constants, quartic distortion constants, and 35Cl quadrupole coupling constants; the RMS deviation of the fit was 1.6 kHz. It is shown that such high-resolution measurements enable [chi]ab to be determined without the near degeneracies usually necessary with less precise data. The principle tensor quadrupole coupling constants are x[chi]zz = -77.46(10), xxx = 38.85(10), and [chi]yy = xcc = 38.614(3) MHz. The values are comparable to other vinyl chlorides, removing some anomalies from previous studies. | en_US |
dc.format.extent | 620398 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | The chlorine nuclear quadrupole coupling tensor in chlorotrifluoroethylene | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationother | Department of Chemistry and Biochemistry, Southern Illinois University. Carbondale, Illinois 62901 | en_US |
dc.contributor.affiliationother | Department of Chemistry, The University of British Columbia, 2036 Main Mall Vancouver, British Columbia. Canada, V6T I Y6 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/27550/1/0000594.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0022-2852(88)90332-3 | en_US |
dc.identifier.source | Journal of Molecular Spectroscopy | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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