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Crosslinking chemistry for high-performance polymer networks
dc.contributor.authorWalker, Kenneth A.en_US
dc.contributor.authorMarkoski, Larry J.en_US
dc.contributor.authorDeeter, Gary A.en_US
dc.contributor.authorSpilman, Gary E.en_US
dc.contributor.authorMartin, David C.en_US
dc.contributor.authorMoore, Jeffrey S.en_US
dc.date.accessioned2006-04-10T17:49:01Z
dc.date.available2006-04-10T17:49:01Z
dc.date.issued1994-11en_US
dc.identifier.citationWalker, Kenneth A., Markoski, Larry J., Deeter, Gary A., Spilman, Gary E., Martin, David C., Moore, Jeffrey S. (1994/11)."Crosslinking chemistry for high-performance polymer networks." Polymer 35(23): 5012-5017. <http://hdl.handle.net/2027.42/31246>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TXW-48CPH85-6N/2/6d7bd81a7bfd9660780acad41741143een_US
dc.identifier.urihttps://hdl.handle.net/2027.42/31246
dc.description.abstractA new thermally reactive monomer has been designed and synthesized that brings novel crosslinking chemistry to high-performance polymers. This monomer (XTA) is a derivative of terephthalic acid and was based on the thermal chemistry of benzocyclobutene. Various model compounds have been synthesized to investigate substituent effects on benzocyclobutene reactivity. Irreversible reaction exotherms around 350[deg]C were observed in these model compounds using differential scanning calorimetry. Based on these studies, polyaramid and poly(aryl ether ketone) XTA copolymers were synthesized. The formation of an insoluble network resulted after heat treatment of these polymers.en_US
dc.format.extent481488 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleCrosslinking chemistry for high-performance polymer networksen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelManagementen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelEconomicsen_US
dc.subject.hlbtoplevelBusinessen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationumMacromolecular Science and Engineering Center, The University of Michigan, Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationumDepartment of Materials Science and Engineering, The University of Michigan, Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationotherDepartment of Chemistry, The University of Illinois at Urbana-Champaign, Urbana, IL 61801, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/31246/1/0000152.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0032-3861(94)90657-2en_US
dc.identifier.sourcePolymeren_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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