Synthesis and characterization of precursors for group II metal aluminates
dc.contributor.author | Narayanan, Ramasubramanian | en_US |
dc.contributor.author | Laine, Richard M. | en_US |
dc.date.accessioned | 2006-04-28T16:51:04Z | |
dc.date.available | 2006-04-28T16:51:04Z | |
dc.date.issued | 1997-10 | en_US |
dc.identifier.citation | Narayanan, Ramasubramanian; Laine, Richrad M. (1997)."Synthesis and characterization of precursors for group II metal aluminates." Applied Organometallic Chemistry 11(10-11): 919-927. <http://hdl.handle.net/2027.42/38300> | en_US |
dc.identifier.issn | 0268-2605 | en_US |
dc.identifier.issn | 1099-0739 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38300 | |
dc.description.abstract | Precursors to Group II metal aluminates (MAI 2 O 4 , M=Mg, Ca, Ba, Sr) are synthesized from inexpensive starting materials including Group II metal oxides/hydroxides, Al(OH) 3 , triethanolamine (TEA) and ethylene glycol, in a one-pot synthesis process. The precursors are soluble in common organic solvents and can be handled in moist air for a reasonable period of time. On pyrolysis in air to 1200 °C, all three precursors transform to the corresponding Group II metal aluminates. A termetallic double alkoxide, ‘ionomer-like’ structure is proposed, wherein the alkaline-earth metal is encapsulated by a TEA molecule bridging two alumatrane units. The precursors were characterized using TGA, NMR, mass spectroscopy and elemental analyses, and the pyrolysed precursors were briefly characterized using x-ray diffraction analysis. © 1997 John Wiley & Sons, Ltd. | en_US |
dc.format.extent | 205126 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Ltd. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Synthesis and characterization of precursors for group II metal aluminates | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Materials Science and Engineering and Department of Chemistry, 2510, G. G. Brown, 2300, Hayward Ave, University of Michigan, Ann Arbor, MI 48109-2136, USA ; Department of Materials Science and Engineering and Department of Chemistry, 2510, G. G. Brown, 2300, Hayward Ave, University of Michigan, Ann Arbor, MI 48109-2136, USA | en_US |
dc.contributor.affiliationum | Department of Materials Science and Engineering and Department of Chemistry, 2510, G. G. Brown, 2300, Hayward Ave, University of Michigan, Ann Arbor, MI 48109-2136, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38300/1/666_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1099-0739(199710/11)11:10/11<919::AID-AOC666>3.0.CO;2-Z | en_US |
dc.identifier.source | Applied Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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