Polyfunctional cubic silsesquioxanes as building blocks for organic/inorganic hybrids
dc.contributor.author | Laine, Richard M. | en_US |
dc.contributor.author | Zhang, Chunxin | en_US |
dc.contributor.author | Sellinger, Alan | en_US |
dc.contributor.author | Viculis, Lisa | en_US |
dc.date.accessioned | 2006-04-28T16:51:27Z | |
dc.date.available | 2006-04-28T16:51:27Z | |
dc.date.issued | 1998-10 | en_US |
dc.identifier.citation | Laine, Richard M.; Zhang, Chunxin; Sellinger, Alan; Viculis, Lisa (1998)."Polyfunctional cubic silsesquioxanes as building blocks for organic/inorganic hybrids." Applied Organometallic Chemistry 12(10-11): 715-723. <http://hdl.handle.net/2027.42/38307> | en_US |
dc.identifier.issn | 0268-2605 | en_US |
dc.identifier.issn | 1099-0739 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38307 | |
dc.description.abstract | Cubic silsesquioxanes, [RSiO 1.5 ] x , potentially offer access to organic/inorganic hybrids wherein the exact shape, size and mechanical properties of the inorganic component are perfectly defined. Furthermore, by tailoring the organic functionality bound to silicon, the inorganic/organic interface can also be perfectly defined. Finally, careful selection of the polymerizable groups in the organic moieties can provide good-to-excellent control of the crosslinked density or degree of polymerization of the resulting hybrid materials. Thus, cubic silsesquioxanes may be exceptional model materials for inorganic/organic hybrids. Methods of synthesizing cubes with liquid-crystalline and/or polymerizable organic moieties are described. Some thermal properties are discussed. The catalytic copolymerization of the octavinyldimethylsiloxy-functionalized cube with the octahydridodimethyl-siloxy-functionalized cube to produce a material with well-defined microporosity and high surface area is described. © 1998 John Wiley & Sons, Ltd. | en_US |
dc.format.extent | 448614 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Ltd. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Polyfunctional cubic silsesquioxanes as building blocks for organic/inorganic hybrids | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Materials Science and Engineering and Department of Chemistry, and the Macromolecular Science and Engineering Center, University of Michigan, Ann Arbor, MI 48109-2136, USA ; Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109-2136, USA | en_US |
dc.contributor.affiliationum | Department of Materials Science and Engineering and Department of Chemistry, and the Macromolecular Science and Engineering Center, University of Michigan, Ann Arbor, MI 48109-2136, USA | en_US |
dc.contributor.affiliationum | Department of Materials Science and Engineering and Department of Chemistry, and the Macromolecular Science and Engineering Center, University of Michigan, Ann Arbor, MI 48109-2136, USA | en_US |
dc.contributor.affiliationum | Department of Materials Science and Engineering and Department of Chemistry, and the Macromolecular Science and Engineering Center, University of Michigan, Ann Arbor, MI 48109-2136, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38307/1/778_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1099-0739(199810/11)12:10/11<715::AID-AOC778>3.0.CO;2-0 | en_US |
dc.identifier.source | Applied Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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